所有图片(1)
About This Item
线性分子式:
(CH3O)2CH(CH2)3CO2CH3
CAS号:
分子量:
176.21
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
96%
表单
liquid
折射率
n20/D 1.422 (lit.)
沸点
70-72 °C/2 mmHg (lit.)
密度
1.012 g/mL at 25 °C (lit.)
官能团
acetal
ester
ether
SMILES字符串
COC(CCCC(=O)OC)OC
InChI
1S/C8H16O4/c1-10-7(9)5-4-6-8(11-2)12-3/h8H,4-6H2,1-3H3
InChI key
YOFAONQHOIRLCQ-UHFFFAOYSA-N
一般描述
Methyl 5,5-dimethoxyvalerate (methyl 5,5-dimethoxypentanoate) is an ester. It can be prepared by reacting methyl 5-oxopentanoate with p-toluene sulfonic acid and trimethylorthoformate. It participates in the synthesis of 1-palmitoyl-2-(5-oxovaleroyl)-sn-glycero-3-phosphatidylcholine.
应用
Methyl 5,5-dimethoxyvalerate may be employed in the synthesis of seven-membered carbocycles. It may be used in the synthesis of 5-(phenylamino)-4-(phenylimino)methyl)-4-pentenoic acid derivatives.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
145.4 °F - closed cup
闪点(°C)
63 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Sanjay Srivastava et al.
The Journal of biological chemistry, 279(51), 53395-53406 (2004-10-07)
Oxidation of unsaturated phospholipids results in the generation of aldehyde side chains that remain esterified to the phospholipid backbone. Such "core" aldehydes elicit immune responses and promote inflammation. However, the biochemical mechanisms by which phospholipid aldehydes are metabolized or detoxified
Formation of seven-membered carbocycles by the use of cyclopropyl silyl ethers as homoenols.
Oleg L Epstein et al.
Angewandte Chemie (International ed. in English), 45(30), 4988-4991 (2006-07-05)
Fangwei Shao et al.
Bioconjugate chemistry, 19(12), 2487-2491 (2008-12-05)
A facile synthetic route to prepare monofunctional carbocyanine dyes for biological application is developed. Three pentamethine carbocyanine dyes have been successfully modified with a variety of functional groups such as: carboxylic acids, azides, or alkynes. The new dyes are characterized
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