所有图片(3)
About This Item
线性分子式:
Zn(ClO4)2·6H2O
CAS号:
分子量:
372.38
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
表单:
crystals and lumps
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![二[双(三氟甲基磺酰)亚胺]锌 95%](/deepweb/assets/sigmaaldrich/product/structures/336/073/952daadd-0a7c-4bec-bbaf-442a24c62161/640/952daadd-0a7c-4bec-bbaf-442a24c62161.png)
表单
crystals and lumps
质量水平
反应适用性
reagent type: oxidant
SMILES字符串
O.O.O.O.O.O.[Zn++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI
1S/2ClHO4.6H2O.Zn/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);6*1H2;/q;;;;;;;;+2/p-2
InChI key
PADPILQDYPIHQQ-UHFFFAOYSA-L
一般描述
高氯酸锌六水合物是锌的六水盐类，在各种有机转化中广泛用作氧化剂和催化剂。也可用于二次电池领域。
应用
高氯酸锌六水合物可作为以下反应的催化剂：
- 缺电子 酚类、空间位阻醇类和胺类的乙酰化。
- 环氧化合物与硫醇开环反应合成2-羟基硫化物。
- 羧酸和醇的无‐溶剂缩合。
- 水基锌电池的电解质。
- 强荧光ZnSe量子点的前体。
警示用语：
Danger
危险声明
危险分类
Ox. Sol. 2 - Skin Corr. 1B
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Highly Efficient Solvent-Free Condensation of Carboxylic Acids with Alcohols Catalysed by Zinc Perchlorate Hexahydrate, Zn(ClO4)2?6 H2O
G Bartoli, et al.
Advanced Synthesis & Catalysis, 347, 33-38 (2005)
Photo-assisted synthesis of highly fluorescent ZnSe(S) quantum dots in aqueous solution
Guo-Yu Lan, et al.
Journal of Materials Chemistry, 17, 2661-2666 (2007)
Zinc perchlorate hexahydrate [Zn(ClO4)2?6H2O] as acylation catalyst for poor nucleophilic phenols, alcohols and amines: Scope and limitations
Shivani, et al.
J. Mol. Catal. A: Chem., 264, 208-213 (2007)
Zinc perchlorate hexahydrate as a new and highly efficient catalyst for synthesis of 2-hydroxysulfides by opening of epoxide rings with thiols under solvent-free conditions: Application for synthesis of the key intermediate of diltiazem
Shivani and Asit K. Chakraborti
J. Mol. Catal. A: Chem., 263, 137-142 (2007)
Ultrastable Zinc Anodes Enabled by Anti-Dehydration Ionic Liquid Polymer Electrolyte for Aqueous Zn Batteries
Jiaqi Huang, et al.
ACS Applied Materials & Interfaces, 13, 4008-4016 (2021)
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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