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Merck
CN

398985

Sigma-Aldrich

N-甲基-1,2-苯二胺

97%

别名:

1-N-甲基苯-1,2-二胺, 2(甲氨基)苯胺, 2-N-甲基苯-1,2-二胺, 2-氨基-N-甲基苯胺, N-甲基-1,2-二氨基苯, N-甲基-1,2-苯二胺, N-甲基邻二氨基苯, N-甲基邻苯二胺, N1-甲基-1,2-苯二胺

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About This Item

线性分子式:
CH3NHC6H4NH2
CAS号:
分子量:
122.17
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.612 (lit.)

沸点

123-124 °C/10 mmHg (lit.)

mp

22 °C (lit.)

密度

1.075 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

CNc1ccccc1N

InChI

1S/C7H10N2/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,8H2,1H3

InChI key

RPKCLSMBVQLWIN-UHFFFAOYSA-N

一般描述

N-甲基-1,2-苯二胺是一种 邻位 -二胺。N-甲基-1,2-苯二胺的原位生成重氮化阳离子曾用于玻碳电极的电化学修饰。

应用

N -甲基-1,2-苯二胺可用于以下研究:
  • 一锅法合成 1-甲基-2-(杂)芳基苯并咪唑。
  • 1-甲基-1 H -苯并咪唑-2(3 H )-硫酮的制备。
  • 血管紧张素 II 受体拮抗剂替米沙坦的全合成。
  • 烯酮二硫代缩醛制备苯并咪唑类。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

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Recent developments in use of heteropolyacids, their salts and polyoxometalates in organic synthesis.
Heravi MM and Sadjadi S.
Journal of the Iranian Chemical Society, 6(1), 1-54 (2009)
Hizbullah Khan et al.
Acta crystallographica. Section E, Structure reports online, 64(Pt 6), o1141-o1141 (2008-01-01)
The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S
A Sanjeev Kumar et al.
Beilstein journal of organic chemistry, 6, 25-25 (2010-05-27)
An efficient synthesis of the angiotensin II receptor antagonist Telmisartan (1) is presented involving a cross coupling of 4-formylphenylboronic acid 10 with 2-(2-bromophenyl)-4,4-dimethyl-2-oxazoline (11) as the key step (90% yield). The benzimidazole moiety 15 was constructed regioselectively via a reductive
Synthesis, 1273-1273 (1992)
Rodrigo Quezada et al.
Nanomaterials (Basel, Switzerland), 10(6) (2020-06-12)
Type of metal and metal-oxide NPs added to modify Thin-Film Composites Reverse Osmosis Membranes (TFC-RO) can alter their anti-biofouling properties by changing the dissolution process. The development of a mathematical model can facilitate the selection of these NPs. This work

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