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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.612 (lit.)
沸点
123-124 °C/10 mmHg (lit.)
mp
22 °C (lit.)
密度
1.075 g/mL at 25 °C (lit.)
官能团
amine
SMILES字符串
CNc1ccccc1N
InChI
1S/C7H10N2/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,8H2,1H3
InChI key
RPKCLSMBVQLWIN-UHFFFAOYSA-N
一般描述
N-甲基-1,2-苯二胺是一种 邻位 -二胺。N-甲基-1,2-苯二胺的原位生成重氮化阳离子曾用于玻碳电极的电化学修饰。
应用
N -甲基-1,2-苯二胺可用于以下研究:
- 一锅法合成 1-甲基-2-(杂)芳基苯并咪唑。
- 1-甲基-1 H -苯并咪唑-2(3 H )-硫酮的制备。
- 血管紧张素 II 受体拮抗剂替米沙坦的全合成。
- 烯酮二硫代缩醛制备苯并咪唑类。
警示用语:
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Recent developments in use of heteropolyacids, their salts and polyoxometalates in organic synthesis.
Journal of the Iranian Chemical Society, 6(1), 1-54 (2009)
Acta crystallographica. Section E, Structure reports online, 64(Pt 6), o1141-o1141 (2008-01-01)
The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S
Beilstein journal of organic chemistry, 6, 25-25 (2010-05-27)
An efficient synthesis of the angiotensin II receptor antagonist Telmisartan (1) is presented involving a cross coupling of 4-formylphenylboronic acid 10 with 2-(2-bromophenyl)-4,4-dimethyl-2-oxazoline (11) as the key step (90% yield). The benzimidazole moiety 15 was constructed regioselectively via a reductive
Synthesis, 1273-1273 (1992)
Nanomaterials (Basel, Switzerland), 10(6) (2020-06-12)
Type of metal and metal-oxide NPs added to modify Thin-Film Composites Reverse Osmosis Membranes (TFC-RO) can alter their anti-biofouling properties by changing the dissolution process. The development of a mathematical model can facilitate the selection of these NPs. This work
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