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安全信息

398195

Sigma-Aldrich

锂 叔 -丁氧 溶液

1.0 M in THF

别名:

tert-Butoxylithium, Lithium 2-methylpropan-2-olate, Lithium t-butoxide, Lithium tert-butylate, Lithium salt of tert-Butyl alcohol

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About This Item

线性分子式:
(CH3)3COLi
CAS号:
1907-33-1
分子量:
80.05
Beilstein:
3620018
MDL编号:
MFCD00050479
UNSPSC代码:
12352300
PubChem化学物质编号:
24864726
NACRES:
NA.22

表单

liquid

质量水平

100

浓度

1.0 M in THF

沸点

67 °C

密度

0.888 g/mL at 25 °C

SMILES字符串

[Li+].CC(C)(C)[O-]

InChI

1S/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1

InChI key

LZWQNOHZMQIFBX-UHFFFAOYSA-N

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应用

锂 叔 -丁氧基溶液在有机合成中一般作为强碱使用。
可用于：
  • 合成导电凝胶电解质用锂改性二氧化硅纳米颗粒。
  • 作为丙交酯开环聚合的催化剂。
  • 作为 LiV 3 O 8 纳米粒子火焰喷雾热解法合成的锂前驱体。

警示用语：

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Central nervous system, Respiratory system

补充剂危害

EUH019

储存分类代码

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

闪点(°F)

-2.2 °F - closed cup

闪点(°C)

-19 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBQ6551
SHBQ6442
SHBQ5870
SHBN5251
SHBM2067

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Electrochemistry of LiV3O8 nanoparticles made by flame spray pyrolysis.
Patey TJ, et al.
Electrochemical and Solid-State Letters, 11(4), A46-A50 (2008)
Solid-phase synthesis of quinoxaline, thiazine, and oxazine analogs through a benzyne intermediate.
Dixon S, et al.
Tetrahedron Letters, 46(43), 7443-7446 (2005)
Efficient and controlled polymerization of lactide under mild conditions with a sodium-based catalyst.
Chen HY, et al.
Green Chemistry, 9(10), 1038-1040 (2007)
Gel electrolytes based on lithium modified silica nano-particles.
Sun J, et al.
Electrochimica Acta, 52(24), 7083-7090 (2007)
Teng-Hao Chen et al.
Nature communications, 5, 5131-5131 (2014-10-14)
Metal-organic and covalent organic frameworks are porous materials characterized by outstanding thermal stability, high porosities and modular synthesis. Their repeating structures offer a great degree of control over pore sizes, dimensions and surface properties. Similarly precise engineering at the nanoscale

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