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一般描述
1,2-Ethanedithiol (1,2-Dimercaptoethane, Dithioglycol, Ethylene mercaptan) is an organo sulfur compound. It affords monomeric, dimeric and polymeric complexes on reaction with Pt(PPh3)4, Pd(PPh3)4 and Ni(PPh3)4. It has been synthesized by refluxing 1,2-dichloroethane with thiourea in ethanol.
应用
1,2-Ethanedithiol may be used in the following studies:
- Synthesis of membrane-permeant, fluorogenic biarsenicals.
- Development of microarrays of protein interaction and quantifying the domain-peptide interactions in high throughput using fluorescently labeled synthetic peptides.
- As insolubilizing agent in a study to evaluate the structural, optical, and electrical properties of high-quality films of PbSe nanocrystals fabricated by a layer-by-layer (LbL) dip-coating method.
- Quantitation of the extent of protein phosphorylation using a phosphoprotein isotope-coded affinity tag (PhIAT).
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
111.2 °F - closed cup
闪点(°C)
44 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis and reactions of new complexes of nickel, palladium, and platinum with 1, 2-ethanedithiol, 2-(methylthio) ethanethiol, and 2-(methylthio) ethane disulfide.
Rauchfuss TB and Roundhill DM.
Journal of the American Chemical Society, 97(12), 3386-3392 (1975)
The vibrational assignment, rotational isomerism and force constants of 1, 2-ethanedithiol.
Hayashi M, et al.
Bulletin of the Chemical Society of Japan, 38(10), 1734-1740 (1965)
M B Goshe et al.
Analytical chemistry, 73(11), 2578-2586 (2001-06-14)
A method has been developed that utilizes phosphoprotein isotope-coded affinity tags (PhIAT) that combines stable isotope and biotin labeling to enrich and quantitatively measure differences in the O-phosphorylation states of proteins. The PhIAT labeling approach involves hydroxide ion-mediated beta-elimination of
Joseph M Luther et al.
ACS nano, 2(2), 271-280 (2009-02-12)
We describe the structural, optical, and electrical properties of high-quality films of PbSe nanocrystals fabricated by a layer-by-layer (LbL) dip-coating method that utilizes 1,2-ethanedithiol (EDT) as an insolubilizing agent. Comparative characterization of nanocrystal films made by spin-coating and by the
Benjamin J Miller et al.
The journal of physical chemistry. A, 114(48), 12692-12700 (2010-11-12)
Vibrational spectra of vapor-phase 1,2-ethanedithiol and 2-mercaptoethanol were recorded to investigate weak intramolecular interactions. The spectra were recorded with conventional absorption spectroscopy and laser photoacoustic spectroscopy in the 2000-11,000 cm(-1) region. The room temperature spectra of each molecule are complicated
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