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Merck
CN

397180

Sigma-Aldrich

三硫代碳酸二甲酯

98%

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About This Item

线性分子式:
(CH3S)2CS
CAS号:
分子量:
138.27
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

表单

liquid

折射率

n20/D 1.675 (lit.)

沸点

101-102 °C/12 mmHg (lit.)

mp

−3 °C (lit.)

密度

1.254 g/mL at 25 °C (lit.)

官能团

thioether

SMILES字符串

CSC(=S)SC

InChI

1S/C3H6S3/c1-5-3(4)6-2/h1-2H3

InChI key

IQWMXKTYXNMSLC-UHFFFAOYSA-N

应用

三硫代碳酸二甲酯可用于以下研究:
  • 甲基-β,β′-二羰基二硫代羧酸酯衍生物的制备。
  • 三(有机硫基)甲基自由基的生成,以及使用EPR光谱法对这些自由基进行评估。
  • β-氧代二硫代羧酸盐的制备。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

206.6 °F - closed cup

闪点(°C)

97 °C - closed cup

个人防护装备

Eyeshields, Gloves


从最新的版本中选择一种:

分析证书(COA)

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A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2, 4-Pentanedione and Some β-Oxoesters.
Oliva A, et al.
Synthetic Communications, 28(18), 3381-3386 (1998)
Gas-Phase Thermolysis, 14. On the Isomerization of Dimethyl Carbonate and Its Mono-, Di-, and Trithio Analogs.
Egsgaard H, et al.
Chemische Berichte, 124(5), 1265-1270 (1999)
A facile method for the synthesis of substituted 2-ylidene-1, 3-oxathioles from acetophenones.
Samuel R, et al.
Tetrahedron Letters, 48(47), 8376-8378 (2007)
An electron paramagnetic resonance study of free-radical additions to trithiocarbonates and of the formation and destruction of tetrathiafulvalene by free-radical processes.
Forrest D and Ingold KU.
Journal of the American Chemical Society, 100(12), 3868-3873 (1978)
Dirk Stueber et al.
Solid state nuclear magnetic resonance, 22(4), 439-457 (2003-01-24)
The 13C chemical shift tensor principal values for the trigonal carbonate and thiocarbonate carbon atoms in the dialkyl carbonates, dimethyl carbonate, ethylene carbonate, and diphenyl carbonate, and in the trithiocarbonates, ethylene trithiocarbonate and dimethyl trithiocarbonate, respectively, were measured in various

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