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About This Item
线性分子式:
H2NNH2 · HBr
CAS号:
分子量:
112.96
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥98%
表单
solid
mp
87-92 °C (lit.)
SMILES字符串
Br.NN
InChI
1S/BrH.H4N2/c;1-2/h1H;1-2H2
InChI key
DVHXJLRODLTJOD-UHFFFAOYSA-N
一般描述
Hydrazine monohydrobromide (hydrazinium bromide) is a hydrobromide salt of hydrazine. It has been prepared by adding aqueous hydrobromic acid to aqueous hydrazine. Its crystal structure has been investigated. It participates in the synthesis of 2-(2′-furoyl)-4(5)-(2′-furanyl)-1H-imidazole (FFI). It is formed as an intermediate during the formation of phosphaminimides from hydrazide derivatives. The fumes from the pyrolysis of hydrazine monohydrobromide soldering flux have been reported to cause dermatitis.
应用
Hydrazine monohydrobromide (hydrazinium bromide) may be used in the synthesis of bromostannates and bromostannites by reacting with tin bromide and also in soldering flux.
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产品编号
说明
价格
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
504. Hydrazine. Part IV. The bromostannates and bromostannites of hydrazine, dimethyl ketazine, and pentan-3-one hydrazone.
Pugh, W
Journal of the Chemical Society, 2491-2493 (1953)
Protection of workers against dermatitis on exposure to hydrazine hydrobromide soldering flux.
Cook WA
International Archives of Occupational and Environmental Health, 13(6), 616-618 (1955)
A Facile Synthesis of an Advanced Glycosylation Endproduct 2-(2'-furoyl)-4 (5)-(2'-furanyl)-1 H-imidazole.
Rho T, et al
Synthetic Communications, 27(24), 4315-4318 (1997)
The crystal structure of hydrazinium bromide, N2H5Br.
Sakurai K and Tomiie Y
Acta Crystallographica, 5(2), 289-289 (1952)
PN compounds 28. Phosphaminimides 3. 4-nitrobenzylation of phosphinyl-1, 1-dimethyl hydrazides and formation of a unique hydrazinium inner salt.
Cates LA and Li VS
Phosph. Sulfur Relat. Elem., 29(2-4), 249-255 (1987)
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