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质量水平
方案
97%
表单
solid
mp
128-130 °C (lit.)
官能团
aldehyde
SMILES字符串
Cc1cc(C=O)c(O)c(C=O)c1
InChI
1S/C9H8O3/c1-6-2-7(4-10)9(12)8(3-6)5-11/h2-5,12H,1H3
InChI key
ZBOUXALQDLLARY-UHFFFAOYSA-N
一般描述
2-Hydroxy-5-methyl-1,3-benzenedicarboxaldehyde (2-hydroxy-5-methylisophthalaldehyde) is a dialdehyde derivative. It has been synthesized by heating p-cresol with hexamethylenetetramine. The structure has been confirmed by 1H and 13C NMR. It is an important raw material for the synthesis of various binucleating schiff base ligand.
应用
2-Hydroxy-5-methyl-1,3-benzenedicarboxaldehyde (2-hydroxy-5-methylisophthalaldehyde) is suitable reagent used in the synthesis of 2-(2′-vinyloxyethoxy)-5-methylisophthaldehyde and chiral calixsalen macrocycles.
2-Hydroxy-5-methyl-1,3-benzenedicarboxaldehyde may be used in the synthesis of the following:
2-Hydroxy-5-methyl-1,3-benzenedicarboxaldehyde may be used in the synthesis of the following:
- 3-[(2,4-Dichlorophenyl)iminomethyl]-2-hydroxy-5-methylbenzaldehyde, a Schiff base.
- 2-Hydroxy-3-methoxymethyl-5-methylbenzaldehyde.
- Acyclic Schiff-base ligands.
- Macrobicyclic ligands (MSB).
- 4-Methyl-2,6-divinylphenol.
- 2-Hydroxy-3-dimethoxymethyl-5-methylbenzaldehyde.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Bimetallic copper (II) and zinc (II) complexes of acyclic Schiff base ligands derived from amino acids.
Arbaoui A, et al
Inorgorganica Chimica Acta, 365(1), 96-102 (2011)
Binuclear metal complexes. 1. Dicopper (II) complexes with binucleating ligands derived from 2-hydroxy-5-methylisophthalaldehyde and 2-(2-aminoethyl) pyridine or histamine.
Grzybowski JJ, et al
Inorganic Chemistry, 17(11), 3078-3082 (1978)
Jian Gao et al.
Inorganic chemistry, 44(2), 232-241 (2005-01-18)
A family of novel chiral "calixsalen" Schiff base macrocycles R,R-H(3)L4, R,R-H(3)L5, containing three chiral diamino moieties were synthesized by an efficient self-assembly and characterized by (1)H and (13)C NMR, mass spectrometry, and X-ray diffraction. The systematic synthesis, structure, and coordination
ESI MS, spectroscopic and semiempirical characterization of a macrobicyclic complex with Er (III) cation.
Przybylski P, et al.
Journal of Molecular Structure, 878(1), 95-103 (2008)
2-Hydroxy-3-methoxymethyl-5-methylbenzaldehyde.
Gunasekaran B, et al
Acta Crystallographica Section E, Structure Reports Online, 69(2), 317-317 (2013)
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