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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.492 (lit.)
沸点
60-63 °C/0.3 mmHg (lit.)
密度
1.062 g/mL at 25 °C (lit.)
官能团
ether
ketone
SMILES字符串
CCOC1=CC(=O)CC1
InChI
1S/C7H10O2/c1-2-9-7-4-3-6(8)5-7/h5H,2-4H2,1H3
InChI key
SUQNVCCJLBQVEI-UHFFFAOYSA-N
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一般描述
3-Ethoxy-2-cyclopentenone (3-Ethoxy-2-cyclopenten-1-one, 3-Ethoxycyclopentenone) is a cyclic β-alkoxy α,β-unsaturated ketone. Its manganese(III) acetate based tandem oxidation has been investigated. Its various physical properties such as density, refractive index and boiling point have been reported.
应用
3-Ethoxy-2-cyclopentenone (3-Ethoxy-2-cyclopenten-1-one) may be used as a starting material in the synthesis of the following:
- allylic cyclopentenyl alcohols like 2-cyclopentenol, 3-methyl-2-cyclopentenol and 3-methoxymethaoxymethyl-2-cyclopentenol
- 3-aminocyclopent-2-en-1-one
- (E)-5-(((2S*,3S*)-3-((benzyloxy)methyl)oxiran-2- yl)methylene)-3-ethoxycyclopent-2-enone, an γ,δ -epoxy-α,β-unsaturated cyclic enone
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
从最新的版本中选择一种:
分析证书(COA)
Manganese (III) acetate based tandem oxidation of various α and β-alkoxy α, β-unsaturated ketones.
Tetrahedron, 58(50), 9983-9988 (2002)
An efficient synthesis of 3-aminocyclopent-2-en-1-one.
Synthesis, 2, 176-176 (1991)
Organic & biomolecular chemistry, 10(28), 5431-5442 (2012-06-19)
We developed a new method for stereoselective construction of an all-carbon quaternary stereogenic center on a carbocyclic ring based on regio- and stereoselective S(N)2' alkylation reactions of γ,δ-epoxy-α,β-unsaturated cyclic ketones. Treatment of the ketones, which were readily prepared in enantiomerically
Palladium-catalyzed rearrangements of 2-cyclopentenyloxypyrimidines in the preparation of pyrimidine carbonucleosides.
Acta Chemica Scandinavica, 47, 72-72 (1993)
596144
CorpBase ID (for auto-filling citation data) null
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