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质量水平
检测方案
97%
形式
solid
mp
210-212 °C (dec.) (lit.)
SMILES字符串
OC(=O)Cc1ccc2ccc3cccc4ccc1c2c34
InChI
1S/C18H12O2/c19-16(20)10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)18(13)17(11)12/h1-9H,10H2,(H,19,20)
InChI key
SDJCLYBBPUHKCD-UHFFFAOYSA-N
一般描述
1-芘乙酸是一种带负电荷的芘衍生物。预期将其用作格氏试剂 和 n -丁基锂 （ n -BuLi）标准化滴定剂。
应用
1-芘乙酸适用于以下研究：
- N -（2-（甲硫基）乙基）-2-（芘-1-基）乙酰胺的合成，基于芘酰胺的 Pd 2 + 探针。
- 芘修饰的 β-环糊精的合成-环糊精。
- 使单壁碳纳米管字段效应晶体管（CNT FET）官能化。
- 作为表征酯官能化聚丙烯接枝率和反应性的试剂。
- 合成锯架式二钌四羰基络合物。
- 手性羧酸（±）-2-（1-芘基）丙酸的合成。
- 单壁碳纳米管的可逆非共价官能化。
- 肽核酸（PNA）探针的制备。
- 作为内引用化合物用于 HPLC-UV 法评估固相反应。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Fushen Lu et al.
Langmuir : the ACS journal of surfaces and colloids, 26(10), 7561-7564 (2010-01-06)
An effective purification method for single-walled carbon nanotubes (SWNTs) based on a combination of oxidative acid treatment and reversible noncovalent functionalization with 1-pyreneacetic acid is reported. The functionalization was selective toward the nanotubes, allowing a nearly complete removal of residual
Ali Khalil et al.
Polymers, 12(8) (2020-08-06)
Hydrophobic and amphiphilic derivatives of the biocompatible and biodegradable poly(dimethylmalic acid) (PdiMeMLA), varying by the nature of the lateral chains and the length of each block, respectively, have been synthesized by anionic ring-opening polymerization (aROP) of the corresponding monomers using
Sawhorse-type diruthenium tetracarbonyl complexes derived from pyrenyl-carboxylic acids.
Johnpeter JP and Therrien B.
Inorgorganica Chimica Acta, 405, 437-443 (2013)
Jan Spengler et al.
ACS combinatorial science, 15(5), 229-234 (2013-03-26)
Here we evaluated the use of internal reference compounds for the rapid assessment of reactions performed in solid-phase. An internal reference compound (commercially available) was bound to the resin, together with the substrate, and cleaved with the products after completion
Gabriela Ramos Chagas et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(23), 3429-3436 (2017-09-01)
A smart stimuli-responsive surface was fabricated by the electro-copolymerization of pyrene monomers followed by base and acid treatment. Copolymers of pyrenes bearing fluorinated chains (Py-nF
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