所有图片(1)
About This Item
线性分子式:
[CH3(CH2)7]3Al
CAS号:
分子量:
366.64
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
浓度
25 wt. % in hexanes
密度
0.701 g/mL at 25 °C
SMILES字符串
CCCCCCCC[Al](CCCCCCCC)CCCCCCCC
InChI
1S/3C8H17.Al/c3*1-3-5-7-8-6-4-2;/h3*1,3-8H2,2H3;
InChI key
LFXVBWRMVZPLFK-UHFFFAOYSA-N
一般描述
三辛基铝溶液是一种有机铝化合物，常用作各种有机合成的反应试剂，包括烷基化、还原和金属化反应。也用作烯烃聚合反应的共催化剂。
应用
三辛基铝溶液（25 wt. %的己烷溶液）可用作序贯阴离子聚合反应制备两亲性嵌段共聚物的反应试剂。
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react 1
靶器官
Central nervous system, Nervous system
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
-5.8 °F - closed cup
闪点(°C)
-21 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Polymer Bull., 15, 127-127 (1986)
Dominic Diether et al.
Dalton transactions (Cambridge, England : 2003), 49(6), 2004-2013 (2020-01-29)
The reaction of 2-(6-methyl-2-pyridyl)-1,1-diphenyl-ethanol [HONCH3] with Ln(AlMe4)3 (Ln = La, Nd, Y) via a deprotonation/C-H-bond activation sequence gave complexes [ONCH2]Ln(AlMe3)2(AlMe4) (Ln = La, Nd, Y) bearing the dianionic tridentate ligand [ONCH2]. In contrast, the reactions involving the smaller rare-earth metals
Dane Christie et al.
ACS central science, 4(4), 504-511 (2018-05-04)
Nanoscale compositional heterogeneity in block copolymers can impart synergistic property combinations, such as stiffness and toughness. However, until now, there has been no experimental method to locally probe the dynamics at a specific location within these structured materials. Here, this
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