385638
二甲基吡啶胺
97%
别名:
双(2-吡啶甲基)胺
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关于此项目
经验公式（希尔记法）:
C12H13N3
化学文摘社编号:
分子量:
199.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
216-266-8
MDL number:
Assay:
97%
产品名称
二甲基吡啶胺, 97%
assay
97%
InChI key
KXZQYLBVMZGIKC-UHFFFAOYSA-N
InChI
1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
SMILES string
C(NCc1ccccn1)c2ccccn2
refractive index
n20/D 1.578 (lit.)
bp
139-141 °C/1 mmHg (lit.)
solubility
water: soluble (partially miscible)(lit.)
density
1.107 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
Application
双（2-吡啶甲基）胺可用作：
- 一种反应物，在三乙胺参与下用 ω-碘脂肪族羧酸酯合成双（2-吡啶甲基氨基）链烷酸酯
- 一种配体，通过用三氯化铁处理来合成双-(2-吡啶甲基)胺的铁络合物，该络合物可用于催化苯直接羟基化为苯酚
- 一种用于保护羧酸的试剂，如双二甲苯基胺的羧酰胺。
General description
二-(2-甲基吡啶)胺(DPA)，2个甲基吡啶取代的二级胺，因具有3个氮原子供体而用作三齿配体。常用于配位化学，与铜(Cu)和镉(Cd)等各种金属离子合成二元、三元和双核配合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Ian Hicks et al.
Molecules (Basel, Switzerland), 25(2) (2020-01-16)
In our current work, we have reported the first cobalt-catalyzed cross-coupling of arylboronic acid with alkyl/aryl phosphites under mild conditions. The reaction was carried out in the presence of zinc powder as an additive and ter-pyridine as a ligand. The
Elena R Milaeva et al.
Dalton transactions (Cambridge, England : 2003), 42(19), 6817-6828 (2013-03-16)
A series of Zn, Mn, Fe, Co, and Ni complexes ([MX2L], X = Cl, OAc) of the novel di-(2-picolyl)amine ligand L with an antioxidant 2,6-di-tert-butylphenol pendant were synthesized and characterized by elemental analysis, IR, multinuclear NMR spectroscopy, MALDI-TOF mass spectrometry
Brandon Clark et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(44), 10099-10112 (2020-06-06)
Extracting valuable products from wastewaters with nitrogen-selective adsorbents can offset energy-intensive ammonia production, rebalance the nitrogen cycle, and incentivize environmental remediation. Separating nitrogen (N) as ammonium from other wastewater cations (e.g., K+ , Ca2+ ) presents a major challenge to
M Stylianou et al.
Dalton transactions (Cambridge, England : 2003), 46(11), 3688-3699 (2017-03-04)
A new two-electron photosensitizer, H
Galina S Matouzenko et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9608-9618 (2011-08-24)
Two polymorphic modifications 1 and 3 of binuclear compound [{Fe(dpia)(NCS)(2)}(2)(bpe)] and pseudo-polymorphic modification [{Fe(dpia)(NCS)(2)}(2)(bpe)]·2CH(3)OH (2), where dpia = di-(2-picolyl)amine, bpe = 1,2-bis(4-pyridyl)ethene, were synthesized, and their structures, magnetic properties, and Mössbauer spectra were studied. Variable-temperature magnetic susceptibility measurements of three
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