384291
二乙基硫代氨基甲酰氯
95%
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关于此项目
线性分子式:
(C2H5)2NCSCl
化学文摘社编号:
分子量:
151.66
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-799-0
MDL number:
Assay:
95%
Form:
solid
InChI key
HUUSTUALCPTCGJ-UHFFFAOYSA-N
InChI
1S/C5H10ClNS/c1-3-7(4-2)5(6)8/h3-4H2,1-2H3
SMILES string
CCN(CC)C(Cl)=S
assay
95%
form
solid
bp
113 °C/10 mmHg (lit.)
mp
45-50 °C (lit.)
functional group
amine, chloro
Quality Level
General description
Diethylthiocarbamoyl chloride is a thiocarbamoyl derivative. It has been reported to participate in the thionation of amides as thionating reagent.
Application
Diethylthiocarbamoyl chloride (N,N′-Diethylthiocarbamoyl chloride) may be used in the following syntheses:
- aryl isothiocyanates
- 5-substituted 4-methyl-2-thiazolyl diethyldithiocarbamates
- novel type of vasorelaxant hybrid compounds
Diethylthiocarbamoyl chloride may be used in the synthesis of 2,6-dimethyl-3,5-dicarbomethoxy-4-(2-difluoromethoxy- 5-isothiocyanatophenyl)-1,4-dihydropyridine.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
L M Yagupolskii et al.
Journal of medicinal chemistry, 42(25), 5266-5271 (1999-12-22)
The synthesis and pharmacological properties of a novel type of vasorelaxant hybrid compounds are described. The investigated compounds originate from fluorinated 4-aryl-1,4-dihydropyridines, which are known calcium channel blockers, and/or from fluorinated analogues of pinacidil, which is an opener of ATP-sensitive
Sulfated tungstate: An efficient catalyst for synthesis of thioamides via Kindler reaction.
Pathare SP, et al.
Applied Catalysis A: General, 425, 125-129 (2012)
The Reaction of Arylamines with Diethylthiocarbamoyl Chloride. A New Synthesis of Aryl Isothiocyanates.
Sayigh AAR, et al.
The Journal of Organic Chemistry, 30(7), 2465-2466 (1965)
K R Frazier et al.
Journal of applied microbiology, 126(1), 79-86 (2018-08-31)
Disulfiram (Antabuse™) and its metabolites formed in vivo were evaluated as antibacterial agents against thirty species of Gram-positive and Gram-negative bacteria. The synergistic potential of disulfiram (DSF) and metabolite diethyldithiocarbamate (DDTC) with approved antibiotics were also compared by isobologram (checkerboard) analysis.
Derivatives of thiazolethiols.
D'Amico JJ, et al.
Journal of the American Chemical Society, 79(19), 5270-5276 (1957)
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