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383473

3-甲酰基-6-甲基色酮

Name: 3-甲酰基-6-甲基色酮
Brand: ALDRICH

97%

别名:

6-甲基-4-氧-4H-1-苯并吡喃-3-甲醛

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About This Item

经验公式（希尔记法）:

C₁₁H₈O₃

CAS号:

42059-81-4

分子量:

188.18

MDL编号:

MFCD00138943

UNSPSC代码:

12352100

PubChem化学物质编号:

24863971

NACRES:

NA.22

质量水平

100

检测方案

97%

形式

solid

mp

172-173 °C (lit.)

SMILES字符串

Cc1ccc2OC=C(C=O)C(=O)c2c1

InChI

1S/C11H8O3/c1-7-2-3-10-9(4-7)11(13)8(5-12)6-14-10/h2-6H,1H3

InChI key

GBWMIOYSMWCYIZ-UHFFFAOYSA-N

一般描述

3-Formyl-6-methylchromone is a 3-formyl-substituted chromone. The combustion calorimetric estimation of the enthalpy of combustion of 3-formyl-6-methylchromone has been reported. Its anti-proliferative action on the MDR human colon cancer and mouse lymphoma has been investigated.

应用

3-Formyl-6-methylchromone has been used for the synthesis of 3-formyl-6-methylchromone-4-phenylthiosemicarbazone.

3-Formyl-6-methylchromone may be used in the preparation of series of Schiff′s bases, via reaction with aromatic sulfonamides, such as sulfanilamide, homosulfanilamide, 4-aminoethyl-benzenesulfonamide, a pyrimidinyl-substituted sulfanilamide derivative, sulfaguanidine and 4-amino-6-trifluoromethyl-benzene-1,3-disulfonamide. It may be used in the preparation of Schiff base, which undergoes addition reaction with diethyl phosphite to afford bis[(1,2,4,3-triazaphospholyl)(chromonyl)aminomethylphosphonate] derivative and bis[(1,2,4,3-triazaphospholyl)(chromonyl)phosphorylamino-methylphosphonate] derivative.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Synthesis, characterization, crystal structure and antimicrobial activity of copper (II) complexes with a thiosemicarbazone derived from 3-formyl-6-methylchromone.

Ilies DC, et al.

Polyhedron, 81, 123-131 (2014)

Synthetic approach for novel bis (a-aminophosphonic acid) derivatives of chromone containing 1, 2, 4, 3-triazaphosphole moieties

Ali, TE and Halacheva, SS.

Heteroatom Chem., 20(3), 117-122 (2009)

Carbonic anhydrase inhibitors. Inhibition of cytosolic/tumor-associated carbonic anhydrase isozymes I, II, IX, and XII with Schiff's bases incorporating chromone and aromatic sulfonamide moieties, and their zinc complexes.

Luca Puccetti et al.

Bioorganic & medicinal chemistry letters, 15(12), 3096-3101 (2005-05-24)

A series of Schiff's bases was prepared by reaction of 3-formyl-chromone or 6-methyl-3-formyl-chromone with aromatic sulfonamides, such as sulfanilamide, homosulfanilamide, 4-aminoethyl-benzenesulfonamide, a pyrimidinyl-substituted sulfanilamide derivative, sulfaguanidine and 4-amino-6-trifluoromethyl-benzene-1,3-disulfonamide. The zinc complexes of these sulfonamides have also been obtained. The new

Metal based biologically active compounds: Design, synthesis, DNA binding and antidiabetic activity of 6-methyl-3-formyl chromone derived hydrazones and their metal (II) complexes.

Jessica Elizabeth Philip et al.

Journal of photochemistry and photobiology. B, Biology, 175, 178-191 (2017-09-12)

Two chromone hydrazone ligands HL

Enthalpies of combustion and formation of 3-formylchromones.

Flores H, et al.

Thermochimica Acta, 450(1), 35-37 (2006)

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