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质量水平
检测方案
99%
形式
solid
bp
126-128 °C/28 mmHg (lit.)
mp
54-56 °C (lit.)
SMILES字符串
CC(=O)c1cc(Cl)ccc1O
InChI
1S/C8H7ClO2/c1-5(10)7-4-6(9)2-3-8(7)11/h2-4,11H,1H3
InChI key
XTGCUDZCCIRWHL-UHFFFAOYSA-N
一般描述
5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) on condensation with salicylhydrazide yields Schiff base, which is reported to form copper(II) complexes. Dipole moment of 5-chloro-2- hydroxyacetophenone has been evaluated in benzene solution.
应用
5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) may be used in the synthesis of:
- 6-chloro-2-methyl-4H-chrome-4-one
- 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
- 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
- 2-styrenyl allyl ether
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
T Keim et al.
Journal of industrial microbiology & biotechnology, 23(4-5), 359-363 (2001-06-26)
Due to their physicochemical and toxicological properties, polychlorinated dibenzofurans are regarded as a class of compounds providing reason for serious environmental concern. While the nonhalogenated basic structure dibenzofuran is effectively mineralized by appropriate bacterial strains, its polychlorinated derivatives are not.
A Highly Efficient and Practical Synthesis of Chromene Derivatives Using Ring-Closing Olefin Metathesis.
Sukbok Chang et al.
The Journal of organic chemistry, 63(3), 864-866 (2001-10-24)
Nicoletta Desideri et al.
Antiviral chemistry & chemotherapy, 14(4), 195-203 (2003-10-30)
Recently, we identified 2-styrylchromones as a new class of antirhinovirus flavonoids with moderate activity against both rhinovirus groups A and B. In order to improve the antiviral effect of the first series of tested 2-styrylchromones, a hydroxy or methoxy group
Synthesis and characterization of copper (II) complexes with a tridentate schiff base ligand derived from 5-chloro-2-hydroxyacetophenone and salicylhydrazide. X-ray structure of copper (II)(5-chloro-2-hydroxyacetophenone-salicylhydrazide) dimethylformamide.
Dance JM, et al.
Inorgorganica Chimica Acta, 162(2), 239-244 (1989)
Studies on the Intramolecular Hydrogen Bond in Conjugated Systems by the Measurements of Dipole Moments. II. Salicylaldehyde and o-Hydroxyacetophenone
Eda B and Ito K.
Bulletin of the Chemical Society of Japan, 30(2), 164-167 (1957)
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