所有图片(1)
About This Item
经验公式（希尔记法）:
C10H18NO3
CAS号:
分子量:
200.25
Beilstein:
3949026
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22
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方案
97%
mp
185-189 °C (lit.)
官能团
carboxylic acid
储存温度
2-8°C
SMILES字符串
CC1(C)CC(CC(C)(C)N1[O])C(O)=O
InChI
1S/C10H18NO3/c1-9(2)5-7(8(12)13)6-10(3,4)11(9)14/h7H,5-6H2,1-4H3,(H,12,13)
InChI key
CYQGCJQJIOARKD-UHFFFAOYSA-N
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一般描述
4-羧基-TEMPO 是 4-取代的 2,2,6,6-四甲基哌啶基-1-氧 (TEMPO) 衍生物。4-羧基-TEMPO 与 3-氨基丙基硅烷固定在介孔二氧化硅表面，组成多相催化系统，用于各种氧化反应。
应用
4-羧基-TEMPO 可用作将再生纤维素（粘胶纤维）氧化为纤维素酸的催化剂。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
G M Rosen et al.
Radiology, 163(1), 239-243 (1987-04-01)
The diagnosis of various disorders of the cerebrospinal fluid (CSF) with magnetic resonance (MR) imaging may require the intrathecal administration of a paramagnetic contrast agent. Furthermore, the CSF route provides direct access to the brain, circumventing the blood-brain barrier. Three
Fei Wang et al.
PloS one, 8(6), e64722-e64722 (2013-06-14)
In this study, the host-guest behavior of poly(amidoamine) (PAMAM) dendrimers bearing amine, hydroxyl, or carboxylate surface functionalities were investigated by paramagnetic NMR studies. 2,2,6,6-Tetramethylpiperidinyloxy (TEMPO) derivatives were used as paramagnetic guest molecules. The results showed that TEMPO-COOH significantly broaden the
Martina Schleicher et al.
International journal of biomaterials, 2012, 397813-397813 (2012-04-07)
In vivo self-endothelialization by endothelial cell adhesion on cardiovascular implants is highly desirable. DNA-oligonucleotides are an intriguing coating material with nonimmunogenic characteristics and the feasibility of easy and rapid chemical fabrication. The objective of this study was the creation of
Dongxiao Wen et al.
International journal of analytical chemistry, 2018, 1710438-1710438 (2018-07-10)
A novel nanocomposite of nanoporous gold nanoparticles (np-AuNPs) functionalized with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO) was prepared; assembled carboxyl groups on gold nanoporous nanoparticles surface were combined with TEMPO by the "bridge" of carboxylate-zirconium-carboxylate chemistry. SEM images and UV-Vis spectroscopies of np-AuNPs
A Michel et al.
The Journal of pharmacy and pharmacology, 41(8), 561-563 (1989-08-01)
The pharmacokinetics of tempo carboxylic acid (TCA), a nitroxyl contrast medium have been evaluated in control and streptozocin-diabetic rats. Previous magnetic resonance imaging (MRI) studies in diabetic rats showed prolongation of contrast visualization in the renal cavities after injection of
商品
TEMPO（2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基）及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现，其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。
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