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Merck
CN

380415

Sigma-Aldrich

三甲基苯氧基硅烷

97%

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别名:
苯基三甲基硅醚, 苯氧基(三甲基)硅烷
线性分子式:
C6H5OSi(CH3)3
CAS号:
分子量:
166.29
Beilstein:
1905943
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

97%

形式

liquid

密度

0.92 g/mL at 25 °C (lit.)

SMILES字符串

C[Si](C)(C)Oc1ccccc1

InChI

1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3

InChI key

OJAJJFGMKAZGRZ-UHFFFAOYSA-N

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一般描述

Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

105.8 °F

闪点(°C)

41 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Trimethylsilyl Protection of Alcohols Over Phosphorus Pentoxide Supported on Silica Gel.
Shaterian HR, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 186(7), 1604-1611 (2011)
Eva Hevia et al.
Chemical communications (Cambridge, England), (22)(22), 3240-3242 (2009-07-10)
A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
STUDIES ON ALCOXYSILANE-ALCOHOL AND PHENOXYSILANE-PHENOL BINARY SYSTEMS.
Nagy J, et al.
Chemical Engineering Journal, 15(3), 155-167 (1971)

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