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方案
97%
表单
liquid
密度
0.92 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)Oc1ccccc1
InChI
1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
InChI key
OJAJJFGMKAZGRZ-UHFFFAOYSA-N
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一般描述
Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
105.8 °F - closed cup
闪点(°C)
41 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
STUDIES ON ALCOXYSILANE-ALCOHOL AND PHENOXYSILANE-PHENOL BINARY SYSTEMS.
Chemical Engineering Journal, 15(3), 155-167 (1971)
Chemical communications (Cambridge, England), (22)(22), 3240-3242 (2009-07-10)
A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
Trimethylsilyl Protection of Alcohols Over Phosphorus Pentoxide Supported on Silica Gel.
Phosphorus, Sulfur, and Silicon and the Related Elements, 186(7), 1604-1611 (2011)
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