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Merck
CN

380229

Sigma-Aldrich

碘甲基甲基醚

contains copper as stabilizer, 95%

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About This Item

线性分子式:
ICH2OCH3
CAS号:
分子量:
171.97
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

95%

表单

liquid

包含

copper as stabilizer

折射率

n20/D 1.546 (lit.)

沸点

39 °C/20 mmHg (lit.)

溶解性

organic solvents: soluble(lit.)

密度

2.03 g/mL at 25 °C (lit.)

官能团

ether
iodo

储存温度

2-8°C

SMILES字符串

COCI

InChI

1S/C2H5IO/c1-4-2-3/h2H2,1H3

InChI key

UUSXSNJAQDJKCG-UHFFFAOYSA-N

一般描述

Iodomethyl methyl ether (Iodomethoxymethane) is a halo ether. Product contains copper as stabilizer. Rotational, centrifugal distortion constants and the nuclear electric quadrupole coupling constant tensor for iodomethyl methyl ether (CH3OCH2I) and its two deuterated species have been measured by microwave spectral studies. It readily undergoes methoxymethylation reaction with phosphorus, carbon, oxygen and nitrogen containing nucleophiles. It can be synthesized by reacting methylal (dimethoxymethane) with iodotrimethylsilane.

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

71.6 °F - closed cup

闪点(°C)

22 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether.
Fujitake M and Hayashi M.
Journal of Molecular Spectroscopy, 128(2), 444-455 (1988)
The carbon-hydrogen bond strength in dimethyl ether and some properties of iodomethyl methyl ether.
Cruickshank FR and Benson SW.
International Journal of Chemical Kinetics, 1(4), 381-390 (1969)
Iodomethyl Methyl Ether
Jung ME, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)

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