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Merck
CN

379387

Sigma-Aldrich

二硫代乙二酰胺

97%

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别名:
乙二硫二胺, 二硫代草酰胺
线性分子式:
NH2CSCSNH2
CAS号:
分子量:
120.20
Beilstein:
605577
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

powder

mp

≥300 °C (lit.)

溶解性

ethanol: soluble 40 mg/10 mL, clear, red

SMILES字符串

NC(=S)C(N)=S

InChI

1S/C2H4N2S2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)

InChI key

OAEGRYMCJYIXQT-UHFFFAOYSA-N

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一般描述

据报道,二硫代草酰胺与 Ni (II) 形成复合物。

应用

二硫代酰胺可用于以下研究:
  • 溶剂热条件下噻唑并噻唑连接的多孔有机聚合物的合成。
  • 以槲皮素为改性剂制备修饰玻碳电极,研究其重要的黄酮类化合物衍生物槲皮素的电化学属性。
  • 用于银离子分离和浓缩的新型二硫代恶胺-甲醛螯合树脂的合成。
  • N,N′ 的合成-二取代二硫代酰胺。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Nickel (II) complexes with dithiooxamide, N, N'-di-methyl-and N, N'-di-hydroxyethyl-dithiooxamide.
Peyronel G, et al.
Inorgorganica Chimica Acta, 5, 627-633 (1971)
Xiang Zhu et al.
Chemical communications (Cambridge, England), 50(95), 15055-15058 (2014-10-21)
Thiazolothiazole-linked porous organic polymers have been synthesized from a facile catalyst-free condensation reaction between aldehydes and dithiooxamide under solvothermal conditions. The resultant porous frameworks exhibit a highly selective uptake of CO2 over N2 under ambient conditions.
Preparation of Dithiooxamide Derivatives.
Hurd RN, et al.
The Journal of Organic Chemistry, 26(10), 3980-3987 (1961)
Ayşen Demir Mülazımoğlu et al.
Sensors (Basel, Switzerland), 12(4), 3916-3928 (2012-06-06)
Electrochemical oxidation of quercetin, as an important biological molecule, has been studied in non-aqueous media using cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. To investigate the electrochemical properties of quercetin, an important flavonoid derivative, on a different surface
H O Desseyn et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(6), 1359-1372 (2003-03-28)
The article describes the vibrational characterization of the secondary thioamide formation and especially a spectroscopical interesting study of different types of hydrogen bonding in NN'-dihydroxyalkyldithiooxamides.

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