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方案
97%
表单
solid
mp
260-262 °C (lit.)
官能团
bromo
SMILES字符串
CC(C)(C)c1cc(Br)c2Oc3c(Br)cc(cc3C(C)(C)c2c1)C(C)(C)C
InChI
1S/C23H28Br2O/c1-21(2,3)13-9-15-19(17(24)11-13)26-20-16(23(15,7)8)10-14(12-18(20)25)22(4,5)6/h9-12H,1-8H3
InChI key
OJJSJAIHWCFVBK-UHFFFAOYSA-N
一般描述
4，5-二溴-2，7-二叔丁基-9，9-二甲基呫吨是杂环结构单元。
应用
4，5-二溴-2，7-二叔丁基-9，9-二甲基呫吨可用于合成：
- 2，6-二叔丁基-4，5-二碘-9，9-二甲基呫吨
- 新的非供体配体，4，5-双（2，6-二异丙基苯胺基）-2，7-二叔丁基-9，9-二甲基呫吨
- 双（二乙氨基）xantphos，通过一锅金属化反应并用双（二乙氨基）氯膦淬灭
4，5-二溴-2，7-二叔丁基-9，9-二甲基呫吨可用作合成4，5-（N，N′-双环己基氨基）-2，7-二叔丁基-9，9-二甲基呫吨和带有两个四噻吩部分的寡噻吩镊子分子的起始试剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Dimethylxanthene-and dibenzofuran-diamido complexes of titanium.
Porter RM and Danopoulos AA.
Polyhedron, 25(4), 859-863 (2006)
Ryo Takita et al.
Organic letters, 10(21), 5003-5005 (2008-10-09)
An oligothiophene tweezer molecule, which has two quaterthiophene moieties connected to create an electrochemically activated hinge, has been synthesized. Two-electron oxidation of the tweezer molecule produces an intramolecular pi-dimer between the two oligothiophene moieties at room temperature as confirmed by
Synthesis, structure, and properties of aromatic ring-layered polymers containing ferrocene as a terminal unit.
Morisaki Y, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 19(1), 104-112 (2009)
Lisa D Julian et al.
Journal of the American Chemical Society, 132(39), 13813-13822 (2010-09-16)
We report a rhodium catalyst that exhibits high reactivity for the hydroamination of primary aminoalkenes that are unbiased toward cyclization and that possess functional groups incompatible with more electrophilic hydroamination catalysts. The rhodium catalyst contains an unusual diaminophosphine ligand (L1)
Extremely Stable Thorium (IV) Dialkyl Complexes Supported by Rigid Tridentate 4, 5-Bis (anilido) xanthene and 2, 6-Bis (anilidomethyl) pyridine Ligands.
Cruz CA, et al.
Organometallics, 26(3), 692-701 (2007)
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