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Merck
CN
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文件

安全信息

378135

Sigma-Aldrich

铍

powder, −325 mesh, ≥99%

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别名:
Glucinium
经验公式（希尔记法）:
Be
CAS号:
7440-41-7
分子量:
9.01
EC 号:
231-150-7
MDL编号:
MFCD00134032
UNSPSC代码:
12352300
PubChem化学物质编号:
24863544

检测方案

≥99%

形式

powder

自燃温度

1198 °F

反应适用性

reagent type: Lewis acid
core: beryllium
reagent type: catalyst

电阻率

4.46 μΩ-cm, 20°C

粒径

−325 mesh

bp

2970 °C (lit.)

mp

1278 °C (lit.)

密度

1.85 g/mL at 25 °C (lit.)

SMILES字符串

[Be]

InChI

1S/Be

InChI key

ATBAMAFKBVZNFJ-UHFFFAOYSA-N

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应用

Starting material for novel sterically encumbered arylberyllium compounds.

Reagent for synthesis of:
  • Beryllium phthalocyanine and its derivatives
  • Catalyst with cerium oxide for oxidative coupling of methane
  • Organoberyllium compounds

Reagent for:
  • Metal mediated dechlorination
  • Stereoselective Horner-Wadsworth-Emmons reactions

象形图

Skull and crossbonesHealth hazard
GHS06,GHS08

警示用语：

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

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I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)
R. Kubiak, et al.,
Inorgorganica Chimica Acta, 359, 1344-1350 (2006)
Renato Winkler et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(44), 17674-17679 (2013-06-27)
Combined measurements of water isotopologues of a snow pit at Vostok over the past 60 y reveal a unique signature that cannot be explained only by climatic features as usually done. Comparisons of the data using a general circulation model
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