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方案
97%
表单
liquid
折射率
n20/D 1.49 (lit.)
沸点
95-98 °C/12 mmHg (lit.)
密度
1.008 g/mL at 25 °C (lit.)
官能团
ether
ketal
phenyl
SMILES字符串
COC(C)(OC)c1ccccc1
InChI
1S/C10H14O2/c1-10(11-2,12-3)9-7-5-4-6-8-9/h4-8H,1-3H3
InChI key
XKSUVRWJZCEYQQ-UHFFFAOYSA-N
一般描述
(1,1-Dimethoxyethyl)benzene is reported to participate in the bismuth triflate catalyzed deprotection of acetals.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
152.6 °F - closed cup
闪点(°C)
67 °C - closed cup
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Marc D Carrigan et al.
The Journal of organic chemistry, 67(3), 1027-1030 (2002-02-22)
Bismuth triflate is a highly efficient catalyst (0.1-1 mol %) for the deprotection of acetals and ketals. The procedure is very facile and selective for acetals derived from ketones and conjugated aldehydes. tert-Butyldimethylsilyl ethers are stable to the reaction conditions.
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