所有图片(2)
About This Item
线性分子式:
HC≡CCH2Si(CH3)3
CAS号:
分子量:
112.24
Beilstein:
2036316
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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一般描述
Trimethyl(propargyl)silane (2-Propynyl-trimethylsilane) is a clear colorless liquid and contains 500ppm of butylated hydroxytoluene (BHT) as stabilizer. It undergoes GaCl3-catalyzed dehydrogenation reaction with aldimines to afford 4-methylquinoline.
应用
Trimethyl(propargyl)silane is suitable for use in the synthesis of diverse end-functionalized (ω-carboxyl, ω-hydroxy, ω-methyl-vinyl, ω-trimethylsilane, and ω-glycidyl-ether) via ′′click′′ reaction. It may be used in the synthesis of γ-allenyl-GABA (γ-aminobutyric acid), via Lewis acid mediated reaction with ω-ethoxy lactams.
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
23.0 °F - closed cup
闪点(°C)
-5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
GaCl3-catalyzed [4+2] annulations of allyltrimethylsilane and trimethyl (propargyl) silane with aldimines.
Hirashita T, et al.
Tetrahedron Letters, 48(31), 5421-5424 (2007)
High yield synthesis of diverse well-defined end-functionalized polymers by combination of anionic polymerization and ?click? chemistry.
Ho C-C, et al.
Journal of Applied Polymer Science, 111(3), 1571-1580 (2009)
Lewis acid induced reactions of propargyl trimethyl silane with ?-ethoxy lactams synthesis of ?-allenyl-GABA.
Hiemstra H, et al.
Tetrahedron Letters, 25(29), 3115-3118 (1984)
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