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检测方案
97%
mp
128-130 °C (lit.)
SMILES字符串
ON=C(C#N)c1ccccc1
InChI
1S/C8H6N2O/c9-6-8(10-11)7-4-2-1-3-5-7/h1-5,11H
InChI key
MJCQFBKIFDVTTR-UHFFFAOYSA-N
应用
2-Hydroxyimino-2-phenylacetonitrile may be used in the synthesis of 2-t-butoxycarbonyloxyimino-2-phenylacetonitrile and o-chlorobenzyloxycarbonylimino-2-phenylacetonitrile.
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
D Scott Bohle et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4223-4229 (2013-02-13)
The reaction of nitric oxide with benzyl cyanide in the presence of potassium methoxide at low temperature gave the dipotassium salt of a bis-diazeniumdiolate 2 in excellent yield. Two new stereospecific syntheses of E or Z 2-(hydroxyimino)-2-phenylacetonitrile from 2 have
A facile method for the preparation of oxime t-butyl carbonates for evaluation of the Beckman rearrangement.
Mamaghani M and Samimi HA.
Orient. J. Chem., 24(3), 837-841 (2008)
Refinement of the crystal structure of 2-hydroxyimino-2-phenylacetonitrile, C8H6N2O, at 173 ?.
Razzino P, et al.
Zeitschrift fur Kristallographie - New Crystal Structures, 216(1-4), 583-584 (2001)
THE SYNTHESIS OF j> METHOXYBENZYLOXYCARBONYL AMINO ACIDS.
Wang K-T.
J. Chin. Chem. Soc., 34, 117-123 (1987)
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