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检测方案
99%
形式
liquid
折射率
n20/D 1.425 (lit.)
bp
110 °C/19 mmHg (lit.)
密度
1.052 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)CC(C)CC(=O)OC
InChI
1S/C8H14O4/c1-6(4-7(9)11-2)5-8(10)12-3/h6H,4-5H2,1-3H3
InChI key
YIJLMTNDXYVGPQ-UHFFFAOYSA-N
一般描述
Dimethyl 3-methylglutarate is an ester. It participates in the synthesis of (R,Z)- muscenone, a valuable perfume ingredient.
应用
用于化学酶法不对称合成的结构单元。
Dimethyl 3-methylglutarate may be used in the synthesis of (R)- and (S)-4-amino-3-methylbutanoic acids, via initial enantioselective hydrolysis with pig liver esterase. It may be used in the preparation of optically active form of verrucarinic acid derivative. It may be used as building block for chemoenzymatic asymmetric synthesis.
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves
Synthesis of Verrucarin A and 3a-Hydroxyverrucarin A from Verrucarol and Diacetoxyscripenol (Anguidine). 39th Communication on Verrucarins and Roridins.
Mohr P, et al.
Helvetica Chimica Acta, 65(5), 1412-1417 (1982)
Tetrahedron, 44, 1477-1477 (1988)
Chemoenzymatic synthesis of (R)-and (S)-4-amino-3-methylbutanoic acids.
Andruszkiewicz R, et al.
Synthetic Communications, 20, 159-166 (1990)
An efficient route to the musk odorant (< i> R</i>,< i> Z</i>)-5-muscenone via base-metal-catalysis.
Lehr K and Furstner A.
Tetrahedron, 68(37), 7695-7700 (2012)
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