375152
苯硒酚
97%
别名:
硒酚, 苯基硒硫醇, 苯基硒酚
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线性分子式:
C6H5SeH
化学文摘社编号:
分子量:
157.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-457-2
Beilstein/REAXYS Number:
385715
MDL number:
产品名称
苯硒酚, 97%
InChI key
WDODWFPDZYSKIA-UHFFFAOYSA-N
InChI
1S/C6H6Se/c7-6-4-2-1-3-5-6/h1-5,7H
SMILES string
[SeH]c1ccccc1
assay
97%
form
liquid
refractive index
n20/D 1.616 (lit.)
bp
71-72 °C/18 mmHg (lit.)
density
1.479 g/mL at 25 °C (lit.)
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Application
在单烯烃基取代的1,3-二烯的合成中，苯砜可以用作起始试剂。可用于合成阳离子硫醇桥联二钌配合物。
General description
苯硒醇是一种芳基硒醇。本文报道了二苯基二硒醚在钨灯照射下能促进苯硒醇自由基加成到灭活的乙炔上。报道了苯乙烯醇催化锡烷介导的自由基链反应，通过二苯基二硒醚与氢化三丁基锡的还原反应原位生成。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
David Crich et al.
Accounts of chemical research, 40(6), 453-463 (2007-05-11)
The discovery and development of the catalysis of stannane-mediated radical chain reactions by benzeneselenol, generated in situ by reduction of diphenyl diselenide with tributyltin hydride, are described. The catalytic sequence is discussed in terms of polarity reversal catalysis of radical
Lorenzo Maserati et al.
Nanoscale, 13(1), 233-241 (2020-12-18)
Hybrid quantum wells are electronic structures where charge carriers are confined along stacked inorganic planes, separated by insulating organic moieties. 2D quantum-confined hybrid materials are of great interest from a solid-state physics standpoint because of the rich many-body phenomena they
Diphenyl diselenide-promoted radical addition of benzeneselenol to acetylenes.
Ogawa A, et al.
Tetrahedron Letters, 33(10), 1329-1332 (1992)
Justin P Johnpeter et al.
Inorganic chemistry, 52(23), 13663-13673 (2013-11-20)
A series of cationic chalcogenolato-bridged diruthenium complexes [(η(6)-p-MeC6H4Pr(i))2Ru2(μ-EC6H5)3](+) (E = S, 1; E = Se, 2; E = Te, 3) has been obtained in ethanol from the reaction of (η(6)-p-MeC6H4Pr(i))2Ru2(μ-Cl)2Cl2 with benzenethiol, benzeneselenol, and sodium tellurophenolate, respectively. The thiolato and
Nikolay V Orlov et al.
The Journal of organic chemistry, 79(24), 12111-12121 (2014-10-08)
A unique Ni-catalyzed transformation is reported for the one-pot highly selective synthesis of previously unknown monoseleno-substituted 1,3-dienes starting from easily available terminal alkynes and benzeneselenol. The combination of a readily available catalyst precursor, Ni(acac)2, and an appropriately tuned phosphine ligand
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