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Merck
CN

375152

苯硒酚

97%

别名:

硒酚, 苯基硒硫醇, 苯基硒酚

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关于此项目

线性分子式:
C6H5SeH
化学文摘社编号:
分子量:
157.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-457-2
Beilstein/REAXYS Number:
385715
MDL number:
Assay:
97%
Form:
liquid
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InChI key

WDODWFPDZYSKIA-UHFFFAOYSA-N

InChI

1S/C6H6Se/c7-6-4-2-1-3-5-6/h1-5,7H

SMILES string

[SeH]c1ccccc1

assay

97%

form

liquid

refractive index

n20/D 1.616 (lit.)

bp

71-72 °C/18 mmHg (lit.)

density

1.479 g/mL at 25 °C (lit.)

General description

苯硒醇是一种芳基硒醇。本文报道了二苯基二硒醚在钨灯照射下能促进苯硒醇自由基加成到灭活的乙炔上。报道了苯乙烯醇催化锡烷介导的自由基链反应,通过二苯基二硒醚与氢化三丁基锡的还原反应原位生成。

Application

在单烯烃基取代的1,3-二烯的合成中,苯砜可以用作起始试剂。可用于合成阳离子硫醇桥联二钌配合物。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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J L Morell et al.
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