374717
2-氟-2-膦酰基乙酸三乙酯
96%
别名:
2-Fluoro-2-phosphonoacetic acid triethyl ester, Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate, Ethyl diethylphosphonofluoroacetate
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所有图片(1)
About This Item
线性分子式:
(C2H5O)2P(O)CH(F)CO2C2H5
CAS号:
分子量:
242.18
Beilstein:
1912161
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
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方案
96%
表单
liquid
反应适用性
reaction type: C-C Bond Formation
折射率
n20/D 1.425 (lit.)
沸点
75 °C/0.01 mmHg (lit.)
密度
1.194 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(=O)C(F)P(=O)(OCC)OCC
InChI
1S/C8H16FO5P/c1-4-12-8(10)7(9)15(11,13-5-2)14-6-3/h7H,4-6H2,1-3H3
InChI key
FVPISMANESAJQZ-UHFFFAOYSA-N
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应用
Reactant for:
- Diels-Alder reactions
- Biosynthesis of terpene
- Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates
- Synthesis of quinolones
- Horner-Wadsworth-Emmons asymmetric hydration
- Addition reactions and the subsequent application to click chemistry
- Asymmetric intermolecular Stetter reactions
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
163.4 °F - closed cup
闪点(°C)
73 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
P W Collins et al.
Journal of medicinal chemistry, 30(11), 1952-1955 (1987-11-01)
A 4-fluoro analogue of enisoprost was prepared and evaluated for gastric antisecretory and mucosal protective activity in animals. The synthesis centered upon cuprate chemistry but also involved a Wittig reaction to produce a cis fluoro olefinic moiety, a furan rearrangement/isomerization
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