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About This Item
线性分子式:
CH3CH(OSO2CF3)CO2C2H5
CAS号:
分子量:
250.19
Beilstein:
3549394
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
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方案
≥96%
旋光性
[α]20/D −44°, neat
包含
~1% MgO as stabilizer
折射率
n20/D 1.374 (lit.)
沸点
34 °C/0.005 mmHg (lit.)
密度
1.342 g/mL at 25 °C (lit.)
官能团
ester
fluoro
triflate
储存温度
−20°C
SMILES字符串
CCOC(=O)[C@H](C)OS(=O)(=O)C(F)(F)F
InChI
1S/C6H9F3O5S/c1-3-13-5(10)4(2)14-15(11,12)6(7,8)9/h4H,3H2,1-2H3/t4-/m0/s1
InChI key
RYSBPHXTNVWICH-BYPYZUCNSA-N
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应用
Ethyl (S)-2-(trifluoromethylsulfonyloxy)propionate can be used:
- In the synthesis of tetra-methylated analog of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTMA) based chelates for imaging applications.
- As a substrate in the synthesis of α-silylated carboxyl compounds via Cu-catalyzed stereoinvertive nucleophilic silylation of α-triflyloxy esters.
警示用语:
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
174.2 °F - closed cup
闪点(°C)
79 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Properties, solution state behavior, and crystal structures of chelates of DOTMA
Aime S, et al.
Inorganic Chemistry, 50(17), 7955-7965 (2011)
Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
Scharfbier J, et al.
Organic Letters, 19(24), 6562-6565 (2017)
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