所有图片(1)
About This Item
线性分子式:
CF3CH2SH
CAS号:
分子量:
116.11
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽压
7.85 psi ( 20 °C)
方案
95%
表单
liquid
折射率
n20/D 1.352 (lit.)
沸点
34-35 °C (lit.)
密度
1.305 g/mL at 25 °C (lit.)
官能团
fluoro
thiol
SMILES字符串
FC(F)(F)CS
InChI
1S/C2H3F3S/c3-2(4,5)1-6/h6H,1H2
InChI key
RYRLLAOLJVDVNN-UHFFFAOYSA-N
相关类别
一般描述
2,2,2-三氟乙硫醇是一种氟化硫醇。研究了 2，2，2-三氟乙硫醇及其氘代分子 CF3CH2SD 的微波光谱。用傅里叶变换离子回旋共振波谱研究了 2，2，2-三氟乙硫醇 (TFET) 的气相酸碱性。采用程序升温段、俄歇电子能谱和红外光谱研究了 2，2，2-三氟乙硫醇在 Mo (110) 表面的反应。
2，2，2-三氟乙硫醇为碱性，与碘分子形成电荷转移络合物。
应用
- Advancements in Peptide Synthesis: A novel synthesis of β-thiol phenylalanine showcases the use of 2,2,2-Trifluoroethanethiol in facilitating one-pot ligation-desulfurization chemistry. This technique is pivotal for developing new peptide-based pharmaceuticals, enhancing both the efficiency and versatility of peptide synthesis (Malins et al., 2015).
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-11.2 °F - closed cup
闪点(°C)
-24 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Intrinsic acidity and basicity of 2, 2, 2-trifluoroethanethiol. The first experimental and theoretical study.
Molina MT, et al.
The Journal of Organic Chemistry, 61(16), 5485-5491 (1996)
Intrinsic (gas-phase) basicities and stability of charge-transfer complexes in solution.
Bouab W, et al.
Journal of Physical Organic Chemistry, 10(5), 343-346 (1997)
Effect of Fluorination on Thiol Reactivity: Reaction of 2, 2, 2-Trifluoroethanethiol on Mo (110).
Napier ME and Friend CM.
The Journal of Physical Chemistry, 99(21), 8750-8757 (1995)
Dong Min Sim et al.
ACS nano, 9(12), 12115-12123 (2015-10-28)
MoS2 is considered a promising two-dimensional active channel material for future nanoelectronics. However, the development of a facile, reliable, and controllable doping methodology is still critical for extending the applicability of MoS2. Here, we report surface charge transfer doping via
Harald Møllendal
The journal of physical chemistry. A, 112(32), 7481-7487 (2008-07-22)
The microwave spectrum of 2,2,2-trifluoroethanethiol, CF3CH2SH, and of one deuterated species, CF3CH2SD, has been investigated in the 7-80 GHz spectral interval. The microwave spectra of the ground and three vibrationally excited states belonging to three different normal modes of one
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