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质量水平
方案
97%
表单
powder or crystals
反应适用性
reagent type: catalyst
core: molybdenum
储存温度
2-8°C
SMILES字符串
Cl[Mo](Cl)(Cl)(Cl)=O
InChI
1S/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4
InChI key
UYEGPKGLVUUIGD-UHFFFAOYSA-J
应用
四氯化钼氧化物可用于：
- 制备用于多种炔烃活性聚合的二元金属催化剂（MoOCl4-n-BuLi）。
- 作为氧化剂用于各种Hantzsch-1,4-二氢吡啶的芳构化反应。
- 作为钼（Mo）前体用于制备nafion-Mo复合材料，其可作为伯胺与醛反应制备硝酮的催化剂。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Nafion supported molybdenum oxychloride: Recyclable catalyst for one-pot synthesis of nitrones via direct condensation/oxidation of primary amines and aldehydes using UHP as oxidant
Singh B, et al.
Green Chemistry, 11(12), 1941-1944 (2009)
Living Polymerization of Substituted Acetylenes by a Novel Binary Catalyst, MoOCl4- n-BuLi
Hayano S and Masuda T
Macromolecules, 31(10), 3170-3174 (1998)
Hayano, S. Masuda, T.
Macromolecules, 31, 3170-3170 (1998)
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
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