37275
(+)-二氢香芹酮
mixture of isomers
别名:
(2R,5R)-5-异丙烯基-2-甲基环己酮
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-872-4
Beilstein/REAXYS Number:
2044615
MDL number:
Form:
liquid
InChI key
AZOCECCLWFDTAP-UHFFFAOYSA-N
InChI
1S/C10H16O/c1-7(2)9-5-4-8(3)10(11)6-9/h8-9H,1,4-6H2,2-3H3
SMILES string
CC1CCC(CC1=O)C(C)=C
form
liquid
optical activity
[α]20/D +20±2°, neat
composition
n-(+)-dihydrocarvone, ~77% , iso-(+)-dihydrocarvone, ~20%
refractive index
n20/D 1.471
density
0.928 g/mL at 20 °C (lit.)
functional group
ketone
Quality Level
General description
(+)-二氢香豆素，一种在香芹籽油中发现的单萜化合物，是合成倍半萜烯的关键结构单元。 它通常通过香芹酮的氢化反应或柠檬烯的氧化反应进行生产。
Application
(+)-二氢香豆素可用于以下过程：
- 合成1,2,4,5-四恶烷，其表现出强效抗疟疾活性。
- 通过氧化反应合成环氧内酯，其可与ε-己内酯发生共聚反应，形成具有形状记忆性能的交联共聚物。
- 合成α-香附酮，一种具有强效杀虫活性的桉叶烷型倍半萜类化合物。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves
Dan Jin et al.
Scientific reports, 10(1), 3309-3309 (2020-02-26)
Cannabis research has historically focused on the most prevalent cannabinoids. However, extracts with a broad spectrum of secondary metabolites may have increased efficacy and decreased adverse effects compared to cannabinoids in isolation. Cannabis's complexity contributes to the length and breadth
Oxidized dihydrocarvone as a renewable multifunctional monomer for the synthesis of shape memory polyesters.
Lowe JR, et al.
Biomacromolecules, 10(7), 2003-2008 (2009)
Insecticidal activity of sesquiterpenes skeleton synthesized by the conventional Robinson annulations reaction on Drosophila melanogaster.
Alarcon J, et al.
Industrial Crops and Products, 42, 268-272 (2013)
The structure and antimalarial activity of dispiro-1, 2, 4, 5-tetraoxanes derived from (+)-dihydrocarvone.
Dong Y, et al.
Bioorganic & Medicinal Chemistry Letters, 20(22), 6359-6361 (2010)
A Convenient Procedure for the Preparation of Dihydrocarvone.
Raucher S and Hwang K-J.
Synthetic Communications, 10(2), 133-137 (1980)
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