检测方案
98%
形式
liquid
折射率
n20/D 1.409 (lit.)
bp
140-142 °C (lit.)
密度
0.798 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)C(=C)O[Si](C)(C)C
InChI
1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3
InChI key
PEHJULPJEVIIFJ-UHFFFAOYSA-N
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一般描述
(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.
应用
(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
75.2 °F
闪点(°C)
24 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl
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