369799
(叔丁氧基羰基亚甲基)三苯基磷烷
98%
别名:
三苯基磷乙酸叔丁酯
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线性分子式:
(C6H5)3P=CHCO2C(CH3)3
化学文摘社编号:
分子量:
376.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
412-880-7
MDL number:
产品名称
(叔丁氧基羰基亚甲基)三苯基磷烷, 98%
InChI key
ZWZUFQPXYVYAFO-UHFFFAOYSA-N
InChI
1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
SMILES string
CC(C)(C)OC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
assay
98%
form
solid
reaction suitability
reaction type: C-C Bond Formation
mp
152-155 °C (lit.)
functional group
ester
phosphine
storage temp.
2-8°C
Quality Level
Application
用于合成醛糖还原酶抑制剂、鬼臼毒素衍生物和互变霉素的 Wittig 试剂。
药物化学中的多功能 Wittig 试剂。
药物化学中的多功能 Wittig 试剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Sens. 1 - STOT RE 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
The Journal of Organic Chemistry, 57, 2922-2922 (1992)
George Kokotos et al.
Journal of medicinal chemistry, 47(14), 3615-3628 (2004-06-25)
The Group IVA cytosolic phospholipase A(2) (GIVA PLA(2)) is a particularly attractive target for drug development because it is the rate-limiting provider of proinflammatory mediators. We previously reported the discovery of novel 2-oxoamides that inhibit GIVA PLA(2) [Kokotos, G.; et
Tetrahedron Letters, 35, 4809-4809 (1994)
B L Mylari et al.
Journal of medicinal chemistry, 35(12), 2155-2162 (1992-06-12)
Benzothiazole side chains featured in zopolrestat (1a) and its congeners were incorporated into oxophthalazineacetic acid replacements, including indazole, pyridazinone, and pyridopyridazinone with a pendant acetic acid moiety. Potent aldose reductase inhibition activity among resulting compounds is as widespread as it
Fritz Sieber et al.
Phosphorus, sulfur, and silicon and the related elements, 180(3-4), 647-657 (2006-02-24)
Elemental selenium generated by the photobleaching of selenomerocyanine dyes forms conjugates with serum albumin and serum lipoproteins that are toxic to leukemia and selected solid tumor cells but well tolerated by normal CD34-positive hematopoietic stem and progenitor cells. Serum albumin
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