所有图片(2)
About This Item
线性分子式:
(C6H5)3P=CHCO2C(CH3)3
CAS号:
分子量:
376.43
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
98%
表单
solid
反应适用性
reaction type: C-C Bond Formation
mp
152-155 °C (lit.)
官能团
ester
phosphine
储存温度
2-8°C
SMILES字符串
CC(C)(C)OC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
InChI key
ZWZUFQPXYVYAFO-UHFFFAOYSA-N
应用
用于合成醛糖还原酶抑制剂、鬼臼毒素衍生物和互变霉素的 Wittig 试剂。
药物化学中的多功能 Wittig 试剂。
药物化学中的多功能 Wittig 试剂。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Sens. 1 - STOT RE 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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The Group IVA cytosolic phospholipase A(2) (GIVA PLA(2)) is a particularly attractive target for drug development because it is the rate-limiting provider of proinflammatory mediators. We previously reported the discovery of novel 2-oxoamides that inhibit GIVA PLA(2) [Kokotos, G.; et
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Tetrahedron Letters, 35, 4809-4809 (1994)
B L Mylari et al.
Journal of medicinal chemistry, 35(12), 2155-2162 (1992-06-12)
Benzothiazole side chains featured in zopolrestat (1a) and its congeners were incorporated into oxophthalazineacetic acid replacements, including indazole, pyridazinone, and pyridopyridazinone with a pendant acetic acid moiety. Potent aldose reductase inhibition activity among resulting compounds is as widespread as it
Fritz Sieber et al.
Phosphorus, sulfur, and silicon and the related elements, 180(3-4), 647-657 (2006-02-24)
Elemental selenium generated by the photobleaching of selenomerocyanine dyes forms conjugates with serum albumin and serum lipoproteins that are toxic to leukemia and selected solid tumor cells but well tolerated by normal CD34-positive hematopoietic stem and progenitor cells. Serum albumin
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