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Merck
CN
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文件

安全信息

368342

Sigma-Aldrich

叠氮化物交换树脂，Amberlite™ IRA-400 负载的叠氮化物

16-50 mesh

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MDL编号:
MFCD00197853
UNSPSC代码:
12352200
NACRES:
NA.22

形式

beads

反应适用性

reaction type: solution phase peptide synthesis

粒径

16-50 mesh

容量

3.8 mmol/g

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应用

Azide exchange resin, azide on Amberlite™ IRA-400 is a resin commonly used to replace activated and nonactivated alkyl halides with azide functional group. It has been used in the synthesis of natural products (±)-oxomaritidine and nornicotine.
It can also be used to prepare:
  • Different imidazolium derived ionic liquid azides.
  • An azide synthon 1-(azidomethyl)-4-[18F]-fluorobenzene, which is used to label an amino acid and a neuropeptide using click chemistry.

法律信息

Amberlite is a trademark of DuPont de Nemours, Inc.

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

补充剂危害

EUH032

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Hassner, A; Stern, M.
Angewandte Chemie (International Edition in English), 25, 478-478 (1986)
Lars C Moeller et al.
Thyroid : official journal of the American Thyroid Association, 19(6), 639-644 (2009-05-19)
Knowledge on the action of thyroid hormone (TH) is augmented by the study of tissue responses to TH in vitro. In order to support the growth of cells in vitro, calf serum (CS) is usually added to the medium to
Synthesis of nornicotine, nicotine and other functionalised derivatives using solid-supported reagents and scavengers
Baxendale IR, et al.
Journal of the Chemical Society. Perkin Transactions 1, 143-154 (2002)
New strategy for the preparation of clickable peptides and labeling with 1-(azidomethyl)-4-[18F]-fluorobenzene for PET
Thonon D, et al.
Bioconjugate Chemistry, 20(4), 817-823 (2009)
A flow process for the multi-step synthesis of the alkaloid natural product oxomaritidine: a new paradigm for molecular assembly
Baxendale IR, et al.
Chemical Communications (Cambridge, England), 2566-2568 (2006)
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Organic Azides and Azide Sources

Since the preparation of the first organic azide, phenyl azide, by Peter Griess in 1864 this energy-rich and versatile class of compounds has enjoyed considerable interest.

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