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Merck
CN

367907

Sigma-Aldrich

三氟甲磺酸钠

98%

别名:

三氟甲基磺酸钠, 三氟甲烷磺酸 钠盐

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About This Item

线性分子式:
CF3SO3Na
CAS号:
分子量:
172.06
Beilstein:
3728797
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

solid

mp

253-255 °C (lit.)

SMILES字符串

[Na+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

XGPOMXSYOKFBHS-UHFFFAOYSA-M

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一般描述

三氟甲烷磺酸钠(三氟甲钠或NaOTf)是一种有效的催化剂,是参与许多有机反应的试剂。其主要应用包括催化不对称曼尼希型反应、水中曼尼希型反应和Diels-Alder反应。它也用作电池中的电解质。

应用

三氟甲磺酸钠可用作制备以下成分的试剂:
  • 芳基氟化物,通过银催化的芳基斯坦酮氟化反应。
  • 离子液体,例如三氟甲磺酸N, N -二烷基吡咯烷鎓,三氟甲磺酸N,N-二烷基咪唑鎓和三氟甲磺酸N-烷基吡啶鎓。

在伯醇与O-保护硫代糖苷的电化学O-糖基化反应中,它还可用作载体电解质。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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