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文件

367508

7-甲氧基-2-萘酚

Name: 7-甲氧基-2-萘酚
Brand: ALDRICH

98%

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About This Item

线性分子式:

CH₃OC₁₀H₆OH

CAS号:

5060-82-2

分子量:

174.20

Beilstein:

2207279

MDL编号:

MFCD00075494

UNSPSC代码:

12352100

PubChem化学物质编号:

24862762

NACRES:

NA.22

质量水平

200

检测方案

98%

mp

116-119 °C (lit.)

SMILES字符串

COc1ccc2ccc(O)cc2c1

InChI

1S/C11H10O2/c1-13-11-5-3-8-2-4-10(12)6-9(8)7-11/h2-7,12H,1H3

InChI key

UNFNRIIETORURP-UHFFFAOYSA-N

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一般描述

7-Methoxy-2-naphthol is a 7-substituted-2-naphthol. Crystal structure of 7-methoxy-2-naphthol has been reported. Reaction of 7-methoxy-2-naphthol with N-methyl-N-phenylhydrazine under thermal conditions has been reported.

应用

7-Methoxy-2-naphthol may be used in the synthesis of new 1H-benzo[f]chromene derivatives. It may be used in the synthesis of 7-methoxy-2-naphthyl (MN)-derived xylosides in which the methoxy group served as a marker for NMR characterization and UV detection.

象形图

GHS07

警示用语：

Warning

危险声明

H315,H319,H335

预防措施声明

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of 9-methoxy and 9-acetoxy-3-amino-1-(4-methoxyphenyl)-1H-benzo [f] chromene-2-carbonitriles via 2-(imino-piperidin-1-yl-methyl)-3-(4-methoxyphenyl) acrylonitrile as intermediate.

El-Agrody AM, et al.

Zeitschrift fur Naturforschung, B: Chemical Sciences, 57(5), 579-585 (2002)

7-Methoxy-2-naphthol.

Prince P, et al.

Acta Crystallographica Section C, Crystal Structure Communications, 47(10), 2218-2220 (1991)

Phosphorylation and sulfation of oligosaccharide substrates critically influence the activity of human beta1,4-galactosyltransferase 7 (GalT-I) and beta1,3-glucuronosyltransferase I (GlcAT-I) involved in the biosynthesis of the glycosaminoglycan-protein linkage region of proteoglycans.

Sandrine Gulberti et al.

The Journal of biological chemistry, 280(2), 1417-1425 (2004-11-04)

We determined whether the two major structural modifications, i.e. phosphorylation and sulfation of the glycosaminoglycan-protein linkage region (GlcAbeta1-3Galbeta1-3Galbeta1-4Xylbeta1), govern the specificity of the glycosyltransferases responsible for the biosynthesis of the tetrasaccharide primer. We analyzed the influence of C-2 phosphorylation of

A new method for N-N bond cleavage of N,N-disubstituted hydrazines to secondary amines and direct ortho amination of naphthol and its analogues.

Qiang Tang et al.

Journal of the American Chemical Society, 130(18), 5840-5841 (2008-04-15)

An unexpected reaction of N,N-disubstituted hydrazine with naphthol and its analogues under simply thermal conditions has been disclosed. 2-Naphthol reacted with various N,N-disubstituted hydrazines under argon to afford 1-amino-2-naphthol and the corresponding secondary amines in excellent yields. Ortho amination of

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