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Merck
CN

367141

Sigma-Aldrich

硒吩

97%

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别名:
Selenacyclopentadiene, Selenofuran
经验公式(希尔记法):
C4H4Se
CAS号:
分子量:
131.03
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

liquid

折射率

n20/D 1.58 (lit.)

bp

110-111 °C (lit.)

mp

−30 °C (lit.)

密度

1.423 g/mL at 25 °C (lit.)

SMILES字符串

c1cc[se]c1

InChI

1S/C4H4Se/c1-2-4-5-3-1/h1-4H

InChI key

MABNMNVCOAICNO-UHFFFAOYSA-N

一般描述

硒酚是一种杂环结构单元。已有报道称使用硒酚合成杂并苯化合物。 已被报道用于合成硒酚-噻吩嵌段共聚物。 已经记录了硒酚在0-6eV能量范围内的电子透射光谱。

应用

硒酚可以用于:
  • 作为有机染料合成中的共轭连接体
  • 合成硒酚-2-甲腈
  • 合成硒酚二酮吡咯并吡咯聚合物
  • 作为导电聚烷基硒酚的结构单元

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 2 - STOT RE 2

WGK

WGK 3

闪点(°F)

26.6 °F

闪点(°C)

-3 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Dye-sensitized solar cells based on organic sensitizers with different conjugated linkers: furan, bifuran, thiophene, bithiophene, selenophene, and biselenophene.
Li R, et al.
The Journal of Physical Chemistry C, 113(17), 7469-7479 (2009)
Low band gap selenophene-diketopyrrolopyrrole polymers exhibiting high and balanced ambipolar performance in bottom-gate transistors.
Shahid M, et al.
Chemical Science, 3(1), 181-185 (2012)
Jon Hollinger et al.
Journal of the American Chemical Society, 132(25), 8546-8547 (2010-06-08)
Selenophene-thiophene block copolymers were synthesized and studied. The properties of these novel block copolymers are distinct from those of statistical copolymers prepared from the same monomers with a similar composition. Specifically, the block copolymers exhibit broad and red-shifted absorbance features
Toshihiro Okamoto et al.
Organic letters, 7(23), 5301-5304 (2005-11-05)
[reaction: see text] A new intramolecular triple cyclization of bis(o-haloaryl)diacetylenes, via dilithiation followed by reaction with chalcogen elements, produces pi-conjugated compounds containing heterole-1,2-dichalcogenin-heterole fused tricyclic skeletons. The subsequent dechalcogenation with copper metal affords a series of thiophene- and selenophene-based heteroacenes.
Journal of the Electrochemical Society, 137, 1827-1827 (1990)

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