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Merck
CN

367044

(3 S )- 顺式 -3,6-二甲基-1,4-二恶烷-2,5-二酮

98%

别名:

L-丙交酯

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关于此项目

经验公式(希尔记法):
C6H8O4
化学文摘社编号:
分子量:
144.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
224-832-0
MDL number:
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产品名称

(3 S )- 顺式 -3,6-二甲基-1,4-二恶烷-2,5-二酮, 98%

InChI key

JJTUDXZGHPGLLC-IMJSIDKUSA-N

InChI

1S/C6H8O4/c1-3-5(7)10-4(2)6(8)9-3/h3-4H,1-2H3/t3-,4-/m0/s1

SMILES string

C[C@@H]1OC(=O)[C@H](C)OC1=O

assay

98%

form

crystals

optical activity

[α]20/D −285°, c = 1 in toluene

mp

92-94 °C (lit.)

functional group

ester

storage temp.

2-8°C

Quality Level

Application

(3S)-顺式-3,6-二甲基-1,4-二恶烷-2,5-二酮可用于合成光学活性的含三吡啶的聚(L-丙交酯)、多分散乳酸低聚物、双环和三环丙交酯衍生物。
用于合成可生物降解的共聚物。

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Biomaterials, 15(3), 189-193 (1994-02-01)
A copolymer of L-lactide and 6-caprolactone (50:50, w/w) was synthesized and characterized. The thermal behaviour of this material did not show any crystallinity for several months; only after more than 1 yr of aging at room temperature and, particularly, in
Xiaohui Zhang et al.
Molecular therapy : the journal of the American Society of Gene Therapy, 25(7), 1606-1615 (2017-02-27)
Neovascular age-related macular degeneration (AMD) is treated with anti-VEGF intravitreal injections, which can cause geographic atrophy, infection, and retinal fibrosis. To minimize these toxicities, we developed a nanoparticle delivery system for recombinant Flt23k intraceptor plasmid (RGD.Flt23k.NP) to suppress VEGF intracellularly
Makromol. Chem., 194, 907-907 (1993)
Monodisperse enantiomeric lactic acid oligomers: preparation, characterization, and stereocomplex formation.
De Jong SJ, et al.
Macromolecules, 31(19), 6397-6402 (1998)
Jun Zhang et al.
Polymers, 11(5) (2019-05-15)
To improve the hemocompatibility of the biodegradable medical poly(ether-ester-urethane) (PEEU), containing uniform-size aliphatic hard segments that was prepared in our lab, a copolymer containing phosphorylcholine (PC) groups was blended with the PEEU. The PC-copolymer of poly(MPC-co-EHMA) (PMEH) was first obtained

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