推荐产品
质量水平
方案
98%
表单
liquid
折射率
n20/D 1.425 (lit.)
沸点
195-198 °C (lit.)
密度
1.294 g/mL at 25 °C (lit.)
官能团
amine
ester
nitro
SMILES字符串
COC(=O)C[N+]([O-])=O
InChI
1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChI key
ALBSWLMUHHZLLR-UHFFFAOYSA-N
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应用
Methyl nitroacetate may be used:
- in the preparation of aromatic and heteroaromatic linear (E)-α-nitro-arylpentenoates
- to generate phenyliodonium ylide, used in the highly enantioselective and diastereoselective Cu(I)-catalyzed cyclopropanation of alkenes
- in the preparation of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate, via reaction with 4-nitrobenzylideneaniline
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
221.0 °F - closed cup
闪点(°C)
105 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Andrew J Young et al.
Journal of the American Chemical Society, 130(43), 14090-14091 (2008-10-04)
The first electrophilic Pd(II)-catalyzed allylic C H alkylation is reported, providing a novel method for formation of sp3-sp3 C C bonds directly from C H bonds. A wide range of aromatic and heteroaromatic linear (E)-alpha-nitro-arylpentenoates are obtained as single olefin
Experimental and theoretical studies of Diels-Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene.
Jasinski R, et al.
Monatshefte fur Chemie / Chemical Monthly, 144(3), 327-335 (2013)
Benoît Moreau et al.
Journal of the American Chemical Society, 127(51), 18014-18015 (2005-12-22)
A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took place with high enantioselectivity for a wide range
[Experimental establishment of the maximum permissible concentration of the methyl and ethyl esters of nitroacetic acid].
G I Sidorin et al.
Gigiena truda i professional'nye zabolevaniia, (7)(7), 49-51 (1980-07-01)
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