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Merck
CN

366404

1,1,4,7,10,10-六甲基三亚乙基四胺

97%

别名:

HMTETA

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关于此项目

线性分子式:
[(CH3)2NCH2CH2N(CH3)CH2-]2
化学文摘社编号:
3083-10-1
分子量:
230.39
EC 号:
221-382-7
MDL编号:
MFCD00025684
UNSPSC代码:
12352100
PubChem化学物质编号:
24862651
NACRES:
NA.22

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质量水平

100

方案

97%

表单

liquid

折射率

n20/D 1.456 (lit.)

沸点

130 °C/11 mmHg (lit.)

密度

0.847 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

CN(C)CCN(C)CCN(C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-9-15(5)11-12-16(6)10-8-14(3)4/h7-12H2,1-6H3

InChI key

DWFKOMDBEKIATP-UHFFFAOYSA-N

相关类别

一般描述

1,1,4,7,10,10-六甲基三乙烯四胺是一种多胺添加剂，已被报告为问题 Koenigs-Knorr 葡萄糖醛酸化的有效试剂。

应用

1,1,4,7,10,10-六甲基三乙烯四胺可用来合成理想的线性无规共聚物。1,1,4,7,10,10-六甲基三乙烯四胺与 CuBr 形成催化络合物，用于原子转移自由基聚合法 (ATRP) 合成聚 [ε-己内酯] 与 N,N-二甲氨基-2-乙基甲基丙烯酸酯单体。它可以作为水溶液中的催化剂，在表面引发的 ATRP 中生成聚 N,N -二甲基丙烯酰胺 (PDMA)。

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

215.6 °F - closed cup

闪点(°C)

102 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV3348
MKCR6686
MKCM9494
MKCJ8395
MKCD2394

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Bryan R Coad et al.
Langmuir : the ACS journal of surfaces and colloids, 23(23), 11791-11803 (2007-10-11)
We report the use of aqueous surface-initiated atom transfer radical polymerization (SI-ATRP) to grow polymer brushes from a "gigaporous" polymeric chromatography support for use as a novel size exclusion chromatography medium. Poly(N,N-dimethylacrylamide) (PDMA) was grown from hydrolyzable surface initiators via
Stefanie L Baker et al.
Nature communications, 10(1), 4718-4718 (2019-10-19)
Almost all commercial proteins are purified using ammonium sulfate precipitation. Protein-polymer conjugates are synthesized from pure starting materials, and the struggle to separate conjugates from polymer, native protein, and from isomers has vexed scientists for decades. We have discovered that
Weihang Ji et al.
Biomacromolecules, 18(8), 2583-2593 (2017-06-29)
Antibacterial polymers are potentially powerful biocides that can destroy bacteria on contact. Debate in the literature has surrounded the mechanism of action of polymeric biocides and the propensity for bacteria to develop resistance to them. There has been particular interest
Masato Mizutani et al.
Journal of the American Chemical Society, 132(21), 7498-7507 (2010-05-12)
All polymerization reactions are categorized into two large different families, chain- and step-growth polymerizations, which are typically incompatible. Here, we report the simultaneous chain- and step-growth polymerization via the metal-catalyzed radical copolymerization of conjugated vinyl monomers and designed monomers possessing
Hsuan-Ying Chen et al.
Colloids and surfaces. B, Biointerfaces, 156, 243-253 (2017-05-24)
Novel comb-shaped amphiphilic copolymers based on methoxy poly(ethylene glycol)-b-[poly(ε-caprolactone)-g-poly(methacrylic acid)] (MPCL-g-pMAA), were synthesized via ring opening polymerization (ROP) and atom transfer radical polymerization (ATRP) for drug delivery systems. MPCL-g-pMAAs with various MAA repeating units self-assemble into a core-shell structure in
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