产品名称
4-碘三氟甲苯, 97%
InChI key
SKGRFPGOGCHDPC-UHFFFAOYSA-N
InChI
1S/C7H4F3I/c8-7(9,10)5-1-3-6(11)4-2-5/h1-4H
SMILES string
FC(F)(F)c1ccc(I)cc1
assay
97%
form
liquid
refractive index
n20/D 1.516 (lit.)
bp
185-186 °C/745 mmHg (lit.)
mp
−8.33 °C (lit.)
density
1.851 g/mL at 25 °C (lit.)
functional group
fluoro
iodo
Quality Level
Application
在与丙烯酸的 Mizoroki-Heck 反应中,4-碘苯并三氟化物可用作具有缺电子芳香环的底物,以得到 4-三氟甲基肉桂酸。
General description
在 DMF 中,用磷酰氯将 4-碘苯三氟化物氨基羰基化,得到 N,N -二甲基-(4-三氟甲基)苯甲酰胺。本文研究了对 -对 -取代苯乙炔与对碘苯三氟化物的无铜薗头交叉偶联反应机理。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Two competing mechanisms for the copper-free Sonogashira cross-coupling reaction.
Ljungdahl T, et al.
Organometallics, 27(11), 2490-2498 (2008)
Kazushi Hosoi et al.
Organic letters, 4(17), 2849-2851 (2002-08-17)
[reaction: see text] Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.
Atsushi Ohtaka et al.
Molecules (Basel, Switzerland), 16(11), 9067-9076 (2011-10-29)
Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled
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