所有图片(1)
About This Item
线性分子式:
C6H5CH(Br)CO2CH3
CAS号:
分子量:
229.07
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.553 (lit.)
bp
113 °C/3 mmHg (lit.)
密度
1.455 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
COC(=O)C(Br)c1ccccc1
InChI
1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
InChI key
NHFBYYMNJUMVOT-UHFFFAOYSA-N
一般描述
Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
应用
Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
235.4 °F
闪点(°C)
113 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide.
Grignard B, et al.
Eur. Polymer J., 44(3), 861-871 (2008)
ESR study on diffusion-controlled atom transfer radical polymerization of methyl methacrylate and ethylene glycol dimethacrylate.
Wang AR and Zhu S.
Macromolecules, 35(27), 9926-9933 (2002)
A novel palladium-catalyzed homocoupling reaction initiated by transmetallation of palladium enolates.
Lei A and Zhang X.
Tetrahedron Letters, 43(14), 2525-2528 (2002)
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