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Merck
CN
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文件

365246

Sigma-Aldrich

2-硝基苯基硒基氰酸酯

97.5%

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别名:
1-Nitro-2-selenocyanatobenzene, o-Nitrophenyl selenocyanate, o-Nitrophenyl selenocyanide, o-Nitrophenylselenyl cyanide
线性分子式:
O2NC6H4SeCN
CAS号:
51694-22-5
分子量:
227.08
Beilstein:
1309777
EC 号:
257-350-4
MDL编号:
MFCD00043146
UNSPSC代码:
12352100
PubChem化学物质编号:
24862498
NACRES:
NA.22

质量水平

200

检测方案

97.5%

mp

140-142 °C (lit.)

SMILES字符串

[O-][N+](=O)c1ccccc1[Se]C#N

InChI

1S/C7H4N2O2Se/c8-5-12-7-4-2-1-3-6(7)9(10)11/h1-4H

InChI key

LHBLJWULWKQRON-UHFFFAOYSA-N

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相关类别

一般描述

2-硝基苯基硒氰酸酯是一种发色团硒化合物。

应用

可使用 2-硝基苯基硒氰酸酯（ o -硝基苯基硒氰酸酯）：
  • 研究其与金属硫蛋白锌/硫醇盐簇发生反应的机制
  • 2,3-开环-5α-胆甾烷-2,3-二醇制备过程中
  • 4α-甲基-2,3-开环-5α-胆甾烷-2,3-二醇制备过程中
  • 2-硝基苯硒基衍生物制备过程中
  • 3α-[（2-硝基苯基）硒] 雄甾-1,5-二烯-17β-ol合成过程中

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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M Arnó et al.
Steroids, 43(3), 305-314 (1984-03-01)
The reaction of 2,3-seco-5 alpha-cholestane-2,3-diol and 4 alpha-methyl-2,3-seco-5 alpha-cholestane-2,3-diol with o-nitrophenyl selenocyanate was studied. The diols were synthesized from cholesterol.
Shaoman Zhou et al.
Journal of medicinal chemistry, 49(20), 6120-6128 (2006-09-29)
All stereoisomers of adenine and guanine methylene-3-fluoromethylenecyclopropane analogues of nucleosides 9a, 9b, 10a, 10b, 11a, 11b, 12a, and 12b were synthesized and their antiviral activities were evaluated. A highly convergent approach permitted the synthesis of all these analogues using a
Synthesis and radical oxidation of steroidal 1-oxo-5α-alcohols.
Khripach VA, et al.
ARKIVOC (Gainesville, FL, United States), 9, 20-28 (2008)
Y Chen et al.
Antioxidants & redox signaling, 3(4), 651-656 (2001-09-14)
Zinc/thiolate (cysteine) coordination occurs in a very large number of proteins. These coordination sites are thermodynamically quite stable. Yet the redox chemistry of thiolate ligands confers extraordinary reactivities on these sites. The significance of such ligand-centered reactions is that they
Wenyi Zheng et al.
Analytical chemistry, 89(14), 7586-7592 (2017-06-24)
p-Xyleneselenocyanate (p-XSC) is one of the most investigated selenium compounds in cancer-prevention and -therapy. Despite the potent anticancer property, there is still no proper method to perform the quantitative analysis of p-XSC in plasma. In this investigation, we aimed at

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