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Merck
CN

365157

Sigma-Aldrich

1,1,3,3-四甲基-1,3-二苯基二硅胺烷

96%

别名:

1,3-联苯基四甲基二硅氮烷, DPTMDS

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About This Item

线性分子式:
[C6H5Si(CH3)2]2NH
CAS号:
分子量:
285.53
Beilstein:
2738118
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

96%

表单

liquid

折射率

n20/D 1.538 (lit.)

沸点

96-100 °C/0.1 mmHg (lit.)

密度

0.985 g/mL at 25 °C (lit.)

SMILES字符串

C[Si](C)(N[Si](C)(C)c1ccccc1)c2ccccc2

InChI

1S/C16H23NSi2/c1-18(2,15-11-7-5-8-12-15)17-19(3,4)16-13-9-6-10-14-16/h5-14,17H,1-4H3

InChI key

HIMXYMYMHUAZLW-UHFFFAOYSA-N

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应用

1,1,3,3-Tetramethyl-1,3-diphenyldisilazane can be used:
  • As a starting material for the synthesis of its substitution products with the tetrachlorides of silicon and tin.
  • To prepare Cu-, Zn- and H2-phthalocyanines using phthalimide.
  • As a pre-column deactivation agent prior to the determination of the fatty acids by GC-MS.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Silazanes plus MCl4-substitution vs. rearrangement reactions
Lehnert C, et al.
Chemistry of Heterocyclic Compounds, 42(12), 1574-1584 (2006)
Convenient synthesis of phthalocyanines with disilazanes under mild conditions.
Uchida H, et al.
ARKIVOC (Gainesville, FL, United States), 11, 17-23 (2005)
Dorothee Eibler et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1046, 138-146 (2017-02-10)
Between 2008 and 2011, four polar bears (Ursus maritimus) from the Greenland population swam and/or drifted on ice to Iceland where they arrived in very poor body condition. Body fat resources in these animals were only between 0% and 10%
Simon Hammann et al.
Analytical and bioanalytical chemistry, 407(30), 9019-9028 (2015-10-07)
Triacylglycerols represent the major part (>90%) in most plant oils and have to be eliminated, when the minor compounds such as phytosterols or tocopherols should be analyzed. Here, we used an all liquid-liquid chromatographic technique, countercurrent chromatography (CCC), to fractionate

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