所有图片(1)
经验公式（希尔记法）:
C12H15NO2 · HCl
CAS号:
分子量:
241.71
Beilstein:
3598081
EC 号:
MDL编号:
UNSPSC代码:
12352209
eCl@ss:
32160406
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
检测方案
98%
旋光性
[α]20/D −48°, c = 1 in H2O
反应适用性
reaction type: solution phase peptide synthesis
mp
148-151 °C (lit.)
应用
peptide synthesis
SMILES字符串
Cl[H].[H][C@]1(CCCN1)C(=O)OCc2ccccc2
InChI
1S/C12H15NO2.ClH/c14-12(11-7-4-8-13-11)15-9-10-5-2-1-3-6-10;/h1-3,5-6,11,13H,4,7-9H2;1H/t11-;/m0./s1
InChI key
NEDMOHHWRPHBAL-MERQFXBCSA-N
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相关类别
应用
广泛用于肽化学中，并在不对称 Diels-Alder 反应中用作手性助剂。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Enantiomeric purity determination of L-proline benzyl ester by chiral column gas chromatography.
M Jemal et al.
Journal of chromatography, 392, 442-446 (1987-04-17)
A Córdova et al.
Bioorganic & medicinal chemistry letters, 9(21), 3119-3122 (1999-11-24)
Mesylates or tosylates of delta-hydroxy-L-norvaline esters spontaneously afford L-proline esters upon exposure to aqueous buffer in near quantitative yield. This novel reaction has led to the development of a simple route to optically active proline esters.
Aldrichimica Acta, 23, 45-45 (1990)
Yukihiro Yamamoto et al.
Applied and environmental microbiology, 76(18), 6180-6185 (2010-08-03)
We specifically examined an exopeptidase, prolyl aminopeptidase (PAP), as a target for synthesis of proline-containing peptides. A PAP from Streptomyces thermoluteus subsp. fuscus NBRC14270 (PAP14270) was obtained using sequence-based screening. From PAP14270, 144Ser was replaced by Cys (scPAP14270) to give
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