所有图片(1)
About This Item
线性分子式:
[C6H5CH(NH2)-]2
CAS号:
分子量:
212.29
Beilstein:
3201645
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
旋光性
[α]20/D −102°, c = 1 in ethanol
光学纯度
ee: 98% (GLC)
mp
83-85 °C (lit.)
官能团
amine
phenyl
SMILES字符串
N[C@H]([C@@H](N)c1ccccc1)c2ccccc2
InChI
1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m0/s1
InChI key
PONXTPCRRASWKW-KBPBESRZSA-N
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一般描述
1,2-二苯基乙二胺是一种手性分子，通常用作手性拆分剂和手性助剂前体。它还可用作NMR研究的手性溶剂化试剂。
应用
形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的 tropocoronand。
包装
无底玻璃瓶。内含物在插入的融合锥体内。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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Science (New York, N.Y.), 367(6478), 671-676 (2020-02-08)
Magnetoelectric (ME) materials combine magnetic and electric polarizabilities in the same phase, offering a basis for developing high-density data storage and spintronic or low-consumption devices owing to the possibility of triggering one property with the other. Such applications require strong
(S,S)-1,2-Diphenylethylenediamine
Chiral Reagents for Asymmetric Synthesis (2003)
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
M Tellier et al.
Journal of pharmaceutical and biomedical analysis, 9(7), 557-563 (1991-01-01)
A new tyrosine-specific LC assay with pre-column fluorogenic derivatization is described for Tyr-Gly as model peptide. o-Hydroxylation of the tyrosine residue with tyrosinase in the presence of ascorbic acid, followed by oxidation to the corresponding quinone by potassium ferricyanide at
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