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Merck
CN

363499

Sigma-Aldrich

1-苯基-1-己炔

99%

别名:

1-己炔基苯

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About This Item

线性分子式:
C6H5C≡C(CH2)3CH3
CAS号:
分子量:
158.24
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

检测方案

99%

形式

solid

折射率

n20/D 1.5349 (lit.)

bp

229-232 °C (lit.)

密度

0.9 g/mL at 25 °C (lit.)

SMILES字符串

CCCCC#Cc1ccccc1

InChI

1S/C12H14/c1-2-3-4-6-9-12-10-7-5-8-11-12/h5,7-8,10-11H,2-4H2,1H3

InChI key

VBRLZTLFLNZEPZ-UHFFFAOYSA-N

一般描述

1-Phenyl-1-hexyne is an alkyne. Stereoselective hydrogenation of 1-phenyl-1-hexyne at 298K and atmospheric pressure of H2 over Pd catalysts supported on mesostructured silica is reported. Polymerization of 1-phenyl-1-hexyne by pentahalides of niobium and tanatalum has been reported. Electrolytically induced, base-catalyzed isomerization of 1-phenyl-1-hexyne to 1-phenyl-1, 2-hexadiene in dimethylformamide containing tetra-n-butylammonium perchlorate using glassy carbon rotating ring-disk electrode has been reported.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

208.4 °F

闪点(°C)

98 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Polymerization of 1-phenyl-1-alkynes by halides of niobium and tantalum.
Masuda T, et al.
Macromolecules, 18(3), 311-317 (1985)
Mesostructured silicas as supports for palladium-catalyzed hydrogenation of phenyl acetylene and 1-phenyl-1-hexyne to alkenes.
Marin-Astorga N, et al.
J. Mol. Catal. A: Chem., 247(1), 145-152 (2006)
Characterization of the electrolytically induced isomerization of 1-phenyl-1-hexyne: Part II. Hydrodynamic voltammetry with rotating disk and ring-disk electrodes.
Stemple JZ and Peters DG.
J. Electroanal. Chem. Interfac. Electrochem., 286(1), 109-121 (1990)

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