推荐产品
方案
98%
表单
liquid
反应适用性
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
密度
0.79 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
CC(C)(C)PC(C)(C)C
InChI
1S/C8H19P/c1-7(2,3)9-8(4,5)6/h9H,1-6H3
InChI key
CRHWEIDCXNDTMO-UHFFFAOYSA-N
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应用
二-叔丁基膦可用于多种配体的合成,如 Q-Phos 的 C-N、C-O 和 C-C 键的交叉偶联反应。
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
No data available
闪点(°C)
No data available
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Palladium-catalyzed ?-arylation of esters and amides under more neutral conditions.
Journal of the American Chemical Society, 125(37), 11176-11177 (2003)
Q-Phos.
Aldrich Chemfiles, 7.10, 12-12 (2007)
A novel functionalized P,C,P pincer ligand complex.
Inorganic Chemistry Communications, 3(10), 511-514 (2000)
Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C? C, C? N, and C? O bond-forming cross-couplings.
The Journal of Organic Chemistry, 67(16), 5553-5566 (2002)
Catalytic C-S Cross-Coupling Reactions Employing Ni Complexes of Pyrrole-Based Pincer Ligands.
ACS Catalysis, 4(9), 2941-2950 (2014)
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