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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.545 (lit.)
沸点
123-124 °C/17 mmHg (lit.)
mp
−60 °C (lit.)
密度
0.957 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)c1ccccc1N
InChI
1S/C10H15N/c1-10(2,3)8-6-4-5-7-9(8)11/h4-7H,11H2,1-3H3
InChI key
AEIOZWYBDBVCGW-UHFFFAOYSA-N
一般描述
2-tert-Butylaniline is a sterically hindered aniline. 2-tert-Butylaniline participates in chemo- and regioselective copper-catalyzed cross-coupling reaction for the effective amination of 2-chlorobenzoic acids.
应用
2-tert-Butylaniline may be used in the preparation of 2,3-bis(2-tert-butylphenylimino)butane. It may be used in the preparation of two rotamers, anti- and syn-N,N′-bis-(2-tert-butylphenyl)naphthalene-1,4,5,8-tetracarboxylic diimides and their guest inclusion abilities were investigated.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
215.6 °F - closed cup
闪点(°C)
102 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
2, 3-Bis (2-tert-butylphenylimino) butane.
Ferreira LC, et al.
Acta Crystallographica Section E, Structure Reports Online, 62(10), o4282-o4284 (2006)
Xuefeng Mei et al.
The Journal of organic chemistry, 71(1), 142-149 (2006-01-04)
[reaction, structure: see text] A chemo- and regioselective copper-catalyzed cross-coupling reaction for effective amination of 2-chlorobenzoic acids with aniline derivatives has been developed. The method eliminates the need for acid protection and produces a wide range of N-aryl anthranilic acid
Difference in guest-inclusion abilities of anti-and syn-rotamers.
Kishikawa K, et al.
Journal of the Chemical Society. Perkin Transactions 1, 14, 2217-2221 (2000)
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