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About This Item
线性分子式:
[(CH3)2CH]3SiC≡CCH3
CAS号:
分子量:
196.40
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
98%
表单
liquid
折射率
n20/D 1.4624 (lit.)
密度
0.82 g/mL at 25 °C (lit.)
SMILES字符串
CC#C[Si](C(C)C)(C(C)C)C(C)C
InChI
1S/C12H24Si/c1-8-9-13(10(2)3,11(4)5)12(6)7/h10-12H,1-7H3
InChI key
FDEZWWXTHRGNJD-UHFFFAOYSA-N
应用
1-(Triisopropylsilyl)-1-propyne may be used in the synthesis of 1,14-diaza[5]helicene. It may be used in the synthesis of 1- and 2-aza[6]helicene, via [2+2+2] cobalt catalyzed trimerization strategy.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
159.8 °F - closed cup
闪点(°C)
71 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Azahelicenes and other similar tri and tetracyclic helical molecules.
Dumitrascu F, et al.
ARKIVOC (Gainesville, FL, United States), 1, 1-32 (2010)
A straightforward route to helically chiral N-heteroaromatic compounds: practical synthesis of racemic 1,14-diaza[5]helicene and optically pure 1- and 2-aza[6]helicenes.
Jirí Mísek et al.
Angewandte Chemie (International ed. in English), 47(17), 3188-3191 (2008-03-14)
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