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方案
98%
表单
liquid
折射率
n20/D 1.4624 (lit.)
密度
0.82 g/mL at 25 °C (lit.)
SMILES字符串
CC#C[Si](C(C)C)(C(C)C)C(C)C
InChI
1S/C12H24Si/c1-8-9-13(10(2)3,11(4)5)12(6)7/h10-12H,1-7H3
InChI key
FDEZWWXTHRGNJD-UHFFFAOYSA-N
应用
1-(Triisopropylsilyl)-1-propyne may be used in the synthesis of 1,14-diaza[5]helicene. It may be used in the synthesis of 1- and 2-aza[6]helicene, via [2+2+2] cobalt catalyzed trimerization strategy.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
159.8 °F - closed cup
闪点(°C)
71 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Azahelicenes and other similar tri and tetracyclic helical molecules.
ARKIVOC (Gainesville, FL, United States), 1, 1-32 (2010)
A straightforward route to helically chiral N-heteroaromatic compounds: practical synthesis of racemic 1,14-diaza[5]helicene and optically pure 1- and 2-aza[6]helicenes.
Angewandte Chemie (International ed. in English), 47(17), 3188-3191 (2008-03-14)
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